Kinetics and Mechanism of the Oxidation of Cyclic Methylsiloxanes by Hydroxyl Radical in the Gas Phase: An Experimental and Theoretical Study
Number of Authors: 6
2015 (English)In: Environmental Science and Technology, ISSN 0013-936X, E-ISSN 1520-5851, Vol. 49, no 22, 13322-13330 p.Article in journal (Refereed) Published
The ubiquitous presence of cyclic volatile methylsiloxanes (cVMS) in the global atmosphere has recently raised environmental concern. In order to assess the persistence and long-range transport potential of cVMS, their second-order rate constants (k) for reactions with hydroxyl radical ((OH)-O-center dot) in the gas phase are needed. We experimentally and theoretically investigated the kinetics and mechanism of (OH)-O-center dot oxidation of a series of cVMS, hexamethylcyclotrisiloxane (D-3), octamethycyclotetrasiloxane (D-4), and decamethycyclopentasiloxane (D-5). Experimentally, we measured k values for D-3, D-4, and D-s -with (OH)-O-center dot in a gas-phase reaction chamber. The Arrhenius activation energies for these reactions in the temperature range from 313 to 353 K were small (-2.92 to 0.79 kcal.mol(-1)), indicating a weak temperature dependence. We also calculated the thermodynamic and kinetic behaviors for reactions at the M06-2X/6-311++G**//M06-2X/6-31+G** level of theory over a wider temperature range of 238-358 K that encompasses temperatures in the troposphere. The calculated Arrhenius activation energies range from -2.71 to -1.64 kcal-mol(-1), also exhibiting weak temperature dependence. The measured k values were approximately an order of magnitude higher than the theoretical values but have the same trend with increasing size of the siloxane ring. The calculated energy barriers for H-atom abstraction at different positions were similar, which provides theoretical support for extrapolating k for other cyclic siloxanes from the number of abstractable hydrogens.
Place, publisher, year, edition, pages
2015. Vol. 49, no 22, 13322-13330 p.
Environmental Engineering Earth and Related Environmental Sciences
IdentifiersURN: urn:nbn:se:su:diva-124756DOI: 10.1021/acs.est.5b03744ISI: 000365151200027PubMedID: 26477990OAI: oai:DiVA.org:su-124756DiVA: diva2:892182