Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation of Propargylic Ketones
Number of Authors: 5
2015 (English)In: ChemCatChem, ISSN 1867-3880, E-ISSN 1867-3899, Vol. 7, no 23, 3818-3821 p.Article in journal (Refereed) Published
The asymmetric transfer hydrogenation of alpha,beta-propargyl ketones catalyzed by an in situ formed ruthenium-hydroxyamide complex was explored. The acetylenic alcohols were isolated in good to excellent yields with excellent ee values (typically >90%) after short reaction times at room temperature.
Place, publisher, year, edition, pages
2015. Vol. 7, no 23, 3818-3821 p.
alkynones, asymmetric catalysis, hydrogenation, propargylic alcohols, ruthenium
IdentifiersURN: urn:nbn:se:su:diva-125785DOI: 10.1002/cctc.201500821ISI: 000366837000002OAI: oai:DiVA.org:su-125785DiVA: diva2:897996