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Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation of Propargylic Ketones
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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2015 (English)In: ChemCatChem, ISSN 1867-3880, E-ISSN 1867-3899, Vol. 7, no 23, 3818-3821 p.Article in journal (Refereed) Published
Abstract [en]

The asymmetric transfer hydrogenation of alpha,beta-propargyl ketones catalyzed by an in situ formed ruthenium-hydroxyamide complex was explored. The acetylenic alcohols were isolated in good to excellent yields with excellent ee values (typically >90%) after short reaction times at room temperature.

Place, publisher, year, edition, pages
2015. Vol. 7, no 23, 3818-3821 p.
Keyword [en]
alkynones, asymmetric catalysis, hydrogenation, propargylic alcohols, ruthenium
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-125785DOI: 10.1002/cctc.201500821ISI: 000366837000002OAI: oai:DiVA.org:su-125785DiVA: diva2:897996
Funder
Knut and Alice Wallenberg FoundationSwedish Research Council
Available from: 2016-01-27 Created: 2016-01-18 Last updated: 2017-03-17Bibliographically approved

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Shatskiy, AndreyKivijärvi, ToveLundberg, HelenaTinnis, FredrikAdolfsson, Hans
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