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Scalable Synthesis of Piperazines Enabled by Visible-Light Irradiation and Aluminum Organometallics
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Number of Authors: 4
2015 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 54, no 47, 14094-14098 p.Article in journal (Refereed) Published
Abstract [en]

The development of more active C-H oxidation catalysts has inspired a rapid, scalable, and stereoselective assembly of multifunctional piperazines through a [3+3] coupling of azomethine ylides. A combination of visible-light irradiation and aluminum organometallics is essential to promote this transformation, which introduces visible-light photochemistry of main-group organometallics and sets the basis for new and promising catalysts.

Place, publisher, year, edition, pages
2015. Vol. 54, no 47, 14094-14098 p.
Keyword [en]
aluminum, cycloaddition, heterocycles, oxidation, photochemistry
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-126408DOI: 10.1002/anie.201505608ISI: 000367722500046PubMedID: 26337253OAI: oai:DiVA.org:su-126408DiVA: diva2:901522
Available from: 2016-02-08 Created: 2016-02-01 Last updated: 2016-02-08Bibliographically approved

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Suarez-Pantiga, SamuelColas, KilianMendoza, Abraham
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ReferencesLink to record
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