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Synthesis of Allenes by Catalytic Coupling of Propargyl Carbonates with Aryl Iodides in the Presence of Diboron Species
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Number of Authors: 2
2016 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 81, no 1, 250-255 p.Article in journal (Refereed) Published
Abstract [en]

Bimetallic copper-/palladium-catalyzed multicomponent reaction of propargyl carbonates, aryl iodides, and diboron species was studied. This procedure can be used for synthesis of di-, tri-, and tetra-substituted allenes. Using diboronic acid, the reaction is supposed to proceed via allenylboronic acid intermediate.

Place, publisher, year, edition, pages
2016. Vol. 81, no 1, 250-255 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-126382DOI: 10.1021/acs.joc.5b01842ISI: 000367701900026PubMedID: 26631028OAI: oai:DiVA.org:su-126382DiVA: diva2:902271
Available from: 2016-02-10 Created: 2016-02-01 Last updated: 2016-02-10Bibliographically approved

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Yang, YuzhuSzabó, Kálmán J.
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