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Palladium-Catalyzed lodofluorination of Alkenes Using Fluorolodoxole Reagent
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Number of Authors: 3
2016 (English)In: ACS Catalysis, ISSN 2155-5435, E-ISSN 2155-5435, Vol. 6, no 1, 447-450 p.Article in journal (Refereed) Published
Abstract [en]

The application of an air- and moisture-stable fluoroiodane reagent was investigated in the palladium-catalyzed iodofluorination reaction of alkenes. Both the iodo and fluoro substituents arise from the fluoroiodane reagent. In the case of certain palladium catalysts, the alkene substrates undergo allylic rearrangement prior to the iodofluorination process. The reaction is faster for electron-rich alkenes than for electron-deficient ones.

Place, publisher, year, edition, pages
2016. Vol. 6, no 1, 447-450 p.
Keyword [en]
fluorination, hypervalent iodines, iodofluorination, palladium catalysis, alkenes, difunctionalization
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-126379DOI: 10.1021/acscatal.5b02022ISI: 000367706800049OAI: oai:DiVA.org:su-126379DiVA: diva2:902962
Available from: 2016-02-12 Created: 2016-02-01 Last updated: 2016-02-12Bibliographically approved

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Ilchenko, Nadia O.Cortes, Miguel A.Szabó, Kálmán J.
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ReferencesLink to record
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