Palladium-Catalyzed lodofluorination of Alkenes Using Fluorolodoxole Reagent
Number of Authors: 3
2016 (English)In: ACS Catalysis, ISSN 2155-5435, E-ISSN 2155-5435, Vol. 6, no 1, 447-450 p.Article in journal (Refereed) Published
The application of an air- and moisture-stable fluoroiodane reagent was investigated in the palladium-catalyzed iodofluorination reaction of alkenes. Both the iodo and fluoro substituents arise from the fluoroiodane reagent. In the case of certain palladium catalysts, the alkene substrates undergo allylic rearrangement prior to the iodofluorination process. The reaction is faster for electron-rich alkenes than for electron-deficient ones.
Place, publisher, year, edition, pages
2016. Vol. 6, no 1, 447-450 p.
fluorination, hypervalent iodines, iodofluorination, palladium catalysis, alkenes, difunctionalization
IdentifiersURN: urn:nbn:se:su:diva-126379DOI: 10.1021/acscatal.5b02022ISI: 000367706800049OAI: oai:DiVA.org:su-126379DiVA: diva2:902962