Olefin-Directed Palladium-Catalyzed Regio- and Stereoselective Hydroboration of Allenes
Number of Authors: 4
2016 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 22, no 9, 2939-2943 p.Article in journal (Refereed) Published
An olefin-directed palladium-catalyzed regio- and stereoselective hydroboration of allenes has been developed to afford fully substituted alkenylboron compounds. The reaction showed a broad substrate scope: a number of functionalized allenes, including 2,3-dienoate, 3,4-dienoate, 3,4-dienol, 1,2-allenylphosphonate, and alkyl-substituted allenes, could be used in this olefin-directed allene hydroboration. The olefin unit was proven to be an indispensable element for this transformation.
Place, publisher, year, edition, pages
2016. Vol. 22, no 9, 2939-2943 p.
allenes, directing group, hydroboration, olefin, palladium
IdentifiersURN: urn:nbn:se:su:diva-127917DOI: 10.1002/chem.201505130ISI: 000370452300015PubMedID: 26710968OAI: oai:DiVA.org:su-127917DiVA: diva2:911740