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Olefin-Directed Palladium-Catalyzed Regio- and Stereoselective Hydroboration of Allenes
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Number of Authors: 4
2016 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 22, no 9, 2939-2943 p.Article in journal (Refereed) Published
Abstract [en]

An olefin-directed palladium-catalyzed regio- and stereoselective hydroboration of allenes has been developed to afford fully substituted alkenylboron compounds. The reaction showed a broad substrate scope: a number of functionalized allenes, including 2,3-dienoate, 3,4-dienoate, 3,4-dienol, 1,2-allenylphosphonate, and alkyl-substituted allenes, could be used in this olefin-directed allene hydroboration. The olefin unit was proven to be an indispensable element for this transformation.

Place, publisher, year, edition, pages
2016. Vol. 22, no 9, 2939-2943 p.
Keyword [en]
allenes, directing group, hydroboration, olefin, palladium
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-127917DOI: 10.1002/chem.201505130ISI: 000370452300015PubMedID: 26710968OAI: oai:DiVA.org:su-127917DiVA: diva2:911740
Available from: 2016-03-14 Created: 2016-03-14 Last updated: 2016-03-14Bibliographically approved

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Zhu, CanYang, BinQiu, YouaiBäckvall, Jan-E.
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