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Catalytic α-Alkylation/Reduction of Ketones with Primary Alcohols To Furnish Secondary Alcohols
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2016 (English)In: Synthesis (Stuttgart), ISSN 0039-7881, E-ISSN 1437-210X, Vol. 48, no 5, 644-652 p.Article, review/survey (Refereed) Published
Abstract [en]

The formation of secondary alcohol products via a tandem -alkylation/transfer hydrogenation of ketones with primary alcohols is a little explored reaction with unrealized potential for green synthesis. This review covers the current literature in the field, including asymmetric versions of the reaction, and outlines future possibilities and challenges for the methodology. 1 Introduction 2 Formation of Racemic Alcohols 3 Formation of Enantiomerically Enriched Alcohols 4 Conclusions

Place, publisher, year, edition, pages
2016. Vol. 48, no 5, 644-652 p.
Keyword [en]
alpha-alkylation, transfer hydrogenation, ketone, alcohol, catalysis, tandem process
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-128530DOI: 10.1055/s-0035-1561315ISI: 000371086100002OAI: oai:DiVA.org:su-128530DiVA: diva2:917297
Available from: 2016-04-06 Created: 2016-03-30 Last updated: 2017-05-27Bibliographically approved

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Lundberg, HelenaAdolfsson, Hans
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