Change search
ReferencesLink to record
Permanent link

Direct link
EMM-26: a two-dimensional medium pore borosilicate zeolitewith 10x10 ring channels solved by rotation electron diffraction
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Show others and affiliations
(English)Manuscript (preprint) (Other academic)
National Category
Chemical Sciences
Research subject
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-128933OAI: oai:DiVA.org:su-128933DiVA: diva2:918029
Available from: 2016-04-08 Created: 2016-04-08 Last updated: 2016-04-08Bibliographically approved
In thesis
1. Structure Determination and Prediction of Zeolites: A Combined Study by Electron Diffraction, Powder X-Ray Diffraction and Database Mining
Open this publication in new window or tab >>Structure Determination and Prediction of Zeolites: A Combined Study by Electron Diffraction, Powder X-Ray Diffraction and Database Mining
2016 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Zeolites are crystalline microporous aluminosilicates with well-defined cavities or channels of molecular dimensions. They are widely used for applications such as gas adsorption, gas storage, ion exchange and catalysis. The size of the pore opening allows zeolites to be categorized into small, medium, large and extra-large pore zeolites. A typical zeolite is the small pore silicoaluminophosphate SAPO-34, which is an important catalyst in the MTO (methanol-to-olefin) process. The properties of zeolite catalysts are determined mainly by their structures, and it is therefore important to know the structures of these materials in order to understand their properties and explore new applications.

Single crystal X-ray diffraction has been the main technique used to determine the structures of unknown crystalline materials such as zeolites. This technique, however, can be used only if crystals larger than several micrometres are available. Powder X-ray diffraction (PXRD) is an alternative technique to determine the structures if only small crystals are available. However, peak overlap, poor crystallinity and the presence of impurities hinder the solution of structures from PXRD data. Electron crystallography can overcome these problems. We have developed a new method, which we have called “rotation electron diffraction” (RED), for the automated collection and processing of three-dimensional electron diffraction data. This thesis describes how the RED method has been applied to determine the structures of several zeolites and zeolite-related materials. These include two interlayer expanded silicates (COE-3 and COE-4), a new layered zeolitic fluoroaluminophosphate (EMM-9), a new borosilicate (EMM-26), and an aluminosilicate (ZSM-25). We have developed a new approach based on strong reflections, and used it to determine the structure of ZSM-25, and to predict the structures of a series of complex zeolites in the RHO family. We propose a new structural principle that describes a series of structurally related zeolites known as “embedded isoreticular zeolite structures”, which have expanding unit cells. The thesis also summarizes several common structural features of zeolites in the Database of Zeolite Structures.

Place, publisher, year, edition, pages
Stockholm: Department of Materials and Environmental Chemistry (MMK), Stockholm University, 2016. 108 p.
Keyword
zeolites, rotation electron diffraction, structure determination, structure prediction, strong reflections approach
National Category
Inorganic Chemistry
Research subject
Inorganic Chemistry
Identifiers
urn:nbn:se:su:diva-127750 (URN)978-91-7649-384-7 (ISBN)
Public defence
2016-05-03, De Geersalen, Geovetenskapens hus, Svante Arrhenius väg 14, Stockholm, 10:00 (English)
Opponent
Supervisors
Note

At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 2: Manuscript. Paper 3: Manuscript.

Available from: 2016-04-08 Created: 2016-03-10 Last updated: 2016-05-17Bibliographically approved

Open Access in DiVA

No full text

Search in DiVA

By author/editor
Guo, PengSun, JunliangZou, Xiaodong
By organisation
Department of Materials and Environmental Chemistry (MMK)
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Total: 91 hits
ReferencesLink to record
Permanent link

Direct link