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A ruthenium water oxidation catalyst based on a carboxamide ligand
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK). China University of Geosciences, China.
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Number of Authors: 7
2016 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 45, no 8, 3272-3276 p.Article in journal (Refereed) Published
Abstract [en]

Herein is presented a single-site Ru complex bearing a carboxamide-based ligand that efficiently manages to carry out the fourelectron oxidation of H2O. The incorporation of the negatively charged ligand framework significantly lowered the redox potentials of the Ru complex, allowing H2O oxidation to be driven by the mild oxidant [Ru(bpy)(3)](3+). This work highlights that the inclusion of amide moieties into metal complexes thus offers access to highly active H2O oxidation catalysts.

Place, publisher, year, edition, pages
2016. Vol. 45, no 8, 3272-3276 p.
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Chemical Sciences
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URN: urn:nbn:se:su:diva-128576DOI: 10.1039/c6dt00327cISI: 000371028600011PubMedID: 26843437OAI: oai:DiVA.org:su-128576DiVA: diva2:935368
Available from: 2016-06-10 Created: 2016-03-30 Last updated: 2016-06-10Bibliographically approved

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Rabten, WangchukÅkermark, TorbjörnKärkäs, Markus D.Chen, HongSun, JunliangAndersson, Pher G.Åkermark, Björn
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Department of Organic ChemistryDepartment of Materials and Environmental Chemistry (MMK)
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