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Formation of C(sp(3))-C(sp(3)) Bonds by Palladium Catalyzed Cross-Coupling of alpha-Diazoketones and Allylboronic Acids
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Number of Authors: 3
2016 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 18, no 10, p. 2503-2506Article in journal (Refereed) Published
Abstract [en]

Palladium catalyzed cross-coupling of allylboronic acids with a-diazoketones was studied. The reaction selectively affords the linear allylic product. The reaction proceeds with formation of a new C(sp(3))-C(sp(3)) bond. The reaction was performed without an external oxidant, likely without the Pd-catalyst undergoing redox reactions.

Place, publisher, year, edition, pages
2016. Vol. 18, no 10, p. 2503-2506
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-132071DOI: 10.1021/acs.orglett.6b01132ISI: 000376476300045PubMedID: 27166509OAI: oai:DiVA.org:su-132071DiVA: diva2:947369
Available from: 2016-07-08 Created: 2016-07-06 Last updated: 2017-11-28Bibliographically approved

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