Selective Heterogeneous C−H Activation/Halogenation Reactions Catalyzed by Pd@MOF Nanocomposites
2016 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 22, no 11, 3729-3737 p.Article in journal (Refereed) Published
A directed heterogeneous C−H activation/halogenation reaction catalyzed by readily synthesized Pd@MOF nanocatalysts was developed. The heterogeneous Pd catalysts used were a novel and environmentally benign Fe-based metal–organic framework (MOF) (Pd@MIL-88B-NH2(Fe)) and the previously developed Pd@MIL-101-NH2(Cr). Very high conversions and selectivities were achieved under very mild reaction conditions and in short reaction times. A wide variety of directing groups, halogen sources, and substitution patterns were well tolerated, and valuable polyhalogenated compounds were synthesized in a controlled manner. The synthesis of the Pd-functionalized Fe-based MOF and the recyclability of the two catalysts are also presented.
Place, publisher, year, edition, pages
2016. Vol. 22, no 11, 3729-3737 p.
Research subject Organic Chemistry
IdentifiersURN: urn:nbn:se:su:diva-132704DOI: 10.1002/chem.201502918ISI: 000371741400027PubMedID: 26481867OAI: oai:DiVA.org:su-132704DiVA: diva2:953873