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  • 1.
    Anderlund, Magnus F.
    et al.
    Stockholm University, Faculty of Science, Department of Organic Chemistry.
    Zheng, J.
    Stockholm University, Faculty of Science, Department of Organic Chemistry.
    Ghiladi, M.
    Stockholm University, Faculty of Science, Department of Organic Chemistry.
    Kritikos, Mikael
    Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK), Inorganic and Structural Chemistry.
    Rivière, Erik
    Sun, Licheng
    Girerd, Jean-Jaques
    Åkermark, Björn
    Stockholm University, Faculty of Science, Department of Organic Chemistry.
    A New, Dinuclear High Spin Manganese(III) Complex with Bridging Phenoxy and Methoxy Groups. Structure and Magnetic Properties2006In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 9, no 12, p. 1195-1198Article in journal (Refereed)
    Abstract [en]

    A new μ-phenoxy-μ-metoxy di-manganese(III) complex with the trisphenolic ligand, 2,6-bis[((2-hydroxybenzyl)(2-pyridylmethyl)amino)methyl]-4-methylphenol, was isolated as a perchlorate salt. The X-ray structure shows that the two manganese(III) ions are in a distorted octrahedral enviroment with approximately perpendicular Jahn–Teller axes. Investigation of the molar magnetic susceptibility reveals a ferromagnetic coupling between the two high-spin manganese(III) ions. Fitting of the data led to g = 2 and J = 12.5 cm−1

  • 2. Xu, Wei-Xia
    et al.
    Zhou, Wei-Xia
    Li, Jun
    Huang, Shi-Liang
    Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
    Niu, Jiao
    Zhang, Feng-Xing
    A novel 3D metal-organic framework with silver iodide anion cluster [Ag14I16](2-) as node: Synthesis, structure, and fluorescence property2014In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 40, p. 220-222Article in journal (Refereed)
    Abstract [en]

    A novel 3D silver iodide metal-organic framework {[Ag14I16(HDABCO)(2)]center dot(DABCO)}(n) (DABCO = 1,4-diazabicyclo[2.2.2]octane) (1) has been synthesized solvothermally. In this compound, a [Ag14I16](2-) anion cluster was formed by twelve AgI4 tetrahedra and two AgI3 triangles by sharing their edges, in which its charge is compensated by two mono-protoned HDABCO(+). Each [Ag14I16](2-) cluster connects to six neighboring clusters by sharing corner I- ions between the AgI4 tetrahedra, resulting in a 3D framework. The compound 1 displays intense fluorescence emission with maximum at 400 nm and 465 nm upon 310 nm excitation at room temperature.

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