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  • 1. Albat, Martin
    et al.
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Stock, Norbert
    Synthesis and crystal structure of three new bismuth(III) arylsulfonatocarboxylates2017Inngår i: Zeitschrift für Kristallographie - Crystalline Materials, ISSN 2194-4946, Vol. 232, nr 1-3, s. 245-253Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Three new bismuth arylsulfonatocarboxylates [Bi(OH)(SB)] (1), [Bi-4(ST)(2)(HST)O-2(H2O)(2)]center dot H2O (2) and [Bi-4(ST)(2)O-3(H2O)(2)] (3) were synthesized under solvothermal reaction conditions at 180 degrees C using the potassium or sodium salt of 4-sulfobenzoic acid (H2SB) and 2-sulfoterephthalic acid (H3ST), respectively. The compounds were characterized in detail and the crystal structures were determined from single crystal X-ray diffraction data. Phase purity was confirmed by powder X-ray diffraction and elemental analysis. Structural comparisons to the only three other known bismuth sulfonatocarboxylates are presented. Due to the higher reaction temperatures employed for the synthesis of the title compounds a higher degree of condensation of the BiOx polyhedra (X = 7 or 8) to tetrameric units, 1D chains or a 2D layer is observed. Connection through the organic linker molecules leads to the formation of 3D coordination polymers in all three title compounds.

  • 2.
    Bartoszewicz, Agnieszka
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Marcos, Rocio
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Sahoo, Suman
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Martín-Matute, Belén
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    A Highly Active Bifunctional Iridium Complex with an Alcohol/Alkoxide-Tethered N-Heterocyclic Carbene for Alkylation of Amines with Alcohols2012Inngår i: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 18, nr 45, s. 14510-14519Artikkel, forskningsoversikt (Fagfellevurdert)
    Abstract [en]

    A series of new iridium(III) complexes containing bidentate N-heterocyclic carbenes (NHC) functionalized with an alcohol or ether group (NHC?OR, R=H, Me) were prepared. The complexes catalyzed the alkylation of anilines with alcohols as latent electrophiles. In particular, biscationic IrIII complexes of the type [Cp*(NHC-OH)Ir(MeCN)]2+2[BF4-] afforded higher-order amine products with very high efficiency; up to >99?% yield using a 1:1 ratio of reactants and 12.5 mol?% of Ir, in short reaction times (216 h) and under base-free conditions. Quantitative yields were also obtained at 50?degrees C, although longer reaction times (4860 h) were needed. A large variety of aromatic amines have been alkylated with primary and secondary alcohols. The reactivity of structurally related iridium(III) complexes was also compared to obtain insights into the mechanism and into the structure of possible catalytic intermediates. The IrIII complexes were stable towards oxygen and moisture, and were characterized by NMR, HRMS, single-crystal X-ray diffraction, and elemental analyses.

  • 3.
    Bonneau, Charlotte
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi.
    Sun, Junliang
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi.
    Sanchez-Smith, Rebeca
    Guo, Bing
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi.
    Zhang, Daliang
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi.
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi.
    Edén, Mattias
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi.
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi.
    Open-Framework Germanate Built from the Hexagonal Packing of Rigid Cylinders2009Inngår i: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 48, nr 21, s. 9962-9964Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    We present a novel open-framework oxide material constructed from Ge10(O,OH)28 (Ge10) oxide clusters prepared via a nonsurfactant route. The material shows two distinct pore windows of 9.43 and 4.65 Å and a low framework density structure of 12.7 Ge atoms per 1000 Å3. The topological study leads to the recognition of a newly observed trinodal 6,7-heterocoordinated net related to the 7-coordinated swh net. The structure displays large rigid cylinders showing features indicating a growth mechanism by hard-sphere packing of the inorganic moiety similar to that observed in mesoporous materials.

  • 4.
    Etman, Ahmed S.
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK). Alexandria University, Egypt.
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Xu, Jiaru
    Younesi, Reza
    Edström, Kristina
    Sun, Junliang
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK). Peking University, China.
    A Water Based Synthesis of Ultrathin Hydrated Vanadium Pentoxide Nanosheets for Lithium Battery Application: Free Standing Electrodes or Conventionally Casted Electrodes?2017Inngår i: Electrochimica Acta, ISSN 0013-4686, E-ISSN 1873-3859, Vol. 252, s. 254-260Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Ultrathin hydrated vanadium pentoxide (V2O5 center dot nH(2)O) nanosheets are fabricated via a water based exfoliation technique. The exfoliation process involves reflux of the precursor, 1:4 mixture of VO2 and V2O5, in water at 80 degrees C for 24 h. Operando and ex situ X-ray diffraction (XRD) studies are conducted to follow the structural changes during the exfoliation process. The chemical and thermal analyses suggest that the molecular formula of the nanosheet is (H0.2V1.8V0.2O5)-V-V-O-IV center dot 0.5H(2)O. The V2O5 center dot nH(2)O nanosheets are mixed with 10% of multi-walled carbon nanotube (MW-CNT) to form a composite material assigned as (VOx-CNT). Free standing electrodes (FSE) and conventionally casted electrodes (CCE) of VOx-CNT are fabricated and then tested as a positive electrode material for lithium batteries. The FSE shows reversible capacities of 300 and 97 mAhg(-1) at current densities of 10 and 200 mAhg(-1), respectively. This is better than earlier reports for free-standing electrodes. The CCE delivers discharge capacities of 175 and 93 mAhg(-1) at current densities of 10 and 200 mAhg(-1), respectively.

  • 5.
    Guo, Bing
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Bonneau, Charlotte
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Sun, Junliang
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Christensen, Kirsten E.
    Yuan, Zhong-Yong
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Investigation of the GeO2-1,6-Diaminohexane-Water-Pyridine-HF Phase Diagram Leading to the Discovery of Two Novel Layered Germanates with Extra-Large Rings2011Inngår i: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 50, nr 1, s. 201-207Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The systematic exploration of the phase diagram of the GeO2-1,6-diaminohexane-water-pyridine-HF system has allowed the identification of specific roles of the HF, H2O contents, and HF/H2O ratio in the formation of Ge7X19 (Ge7), Ge9X25−26 (Ge9), and Ge10X28 (Ge10) clusters (X = O, OH, F). This work has led to the discovery of two novel structures with extra-large 18-membered rings accommodating 1,6-diaminohexane (DAH): SU-63, |1.5H2DAH|[Ge7O14X3]·2H2O, a layered germanate constructed from Ge7 clusters with the Kagom topology, and SU-64, |11H2DAH|[Ge9O18X4][Ge7O14X3]6·16H2O, a germanate built of two-dimensional slabs containing both Ge7 and Ge9 clusters (X = OH or F). We also put SU-64 in context with previously reported cluster germanate compounds with related topologies by means of a simple crystal deconstruction study.

  • 6. Halis, Seida
    et al.
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Dehning, Niklas
    Weyrich, Thomas
    Reinsch, Helge
    Stock, Norbert
    Dihydroxybenzoquinone as Linker for the Synthesis of Permanently Porous Aluminum Metal-Organic Frameworks2016Inngår i: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 55, nr 15, s. 7425-7431Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Two new dihydroxybenzoquinone-based metal-organic frameworks, ((CH3)(2)NH2)(3)[Al-4(L1)(3)(L1(center dot))(3)]center dot 3DMF (1, denoted CAU - 20) and ((CH3)(2)NH2)(3)[Al-4(L2)(3)(L2 center dot)(3)]center dot 9DMF (2, denoted CAU-20-Cl-2), were synthesized at 120 degrees C in PAU using 2,5-dihydroxy-p-benzoquinone ((C6H2(OH)(2)(O)(2)), H(2)L1) and 2,5-dichloro-3,6-dihydroxy-p-benzoquinone ((C6Cl2(OH)(2)(O)(2)), H(2)L2), respectively. Compared to other Al-MOFs, which contain carboxylate or phosphonate groups that connect the metal sites, in 1 and 2 the Al3+ are coordinated by oxido groups. The metal ions are octahedrally surrounded by oxygen atoms Of the deprotonated linker molecules to generate honeycomb layers with a metal to linker ratio of Al: L1/L2 = 2:3. The layers contain L1(2-) and L2(2-) ions as well as linker radical ions L1(center dot 3-) and L2(center dot 3-) in a molar ratio of 1 to 1. The presence of radical ions was confirmed by EPR and UV-vis-spectroscopic Measurements, and the composition was determined from a combination of PXRD, H-1, NMR, TG, and elemental analyses. Charge balance is accomplished through intercalation of (CH3)(2)NH2+ ions which are formed by partial hydrolysis of DMF. In the structures of 1 and 2 the eclipsed layers are AA and ABAB stacked, respectively, and one-dimensional hexagonal channels with diameters of ca. 9 and 6 angstrom are formed. Both compounds exhibit permanent porosity and have specific surface areas of 1440 and 1430 m(2) g(-1), respectively.

  • 7. Heidenreich, N.
    et al.
    Rütt, U.
    Köppen, M.
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Beier, S.
    Dippel, A. -C.
    Suren, R.
    Stock, N.
    A multi-purpose reaction cell for the investigation of reactions under solvothermal conditions2017Inngår i: Review of Scientific Instruments, ISSN 0034-6748, E-ISSN 1089-7623, Vol. 88, nr 10, artikkel-id 104102Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A new versatile and easy-to-use remote-controlled reactor setup aimed at the analysis of chemical reactions under solvothermal conditions has been constructed. The reactor includes a heating system that can precisely control the temperature inside the reaction vessels in a range between ambient temperature and 180 degrees C. As reaction vessels, two sizes of commercially available borosilicate vessels (V-max = 5 and 11 ml) can be used. The setup furthermore includes the option of stirring and injecting of up to two liquid additives or one solid during the reaction to initiate very fast reactions, quench reactions, or alter chemical parameters. In addition to a detailed description of the general setup and its functionality, three examples of studies conducted using this setup are presented.

  • 8.
    Huang, Shiliang
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Yang, Sihai
    Christensen, Kirsten E.
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Sun, Junliang
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    SU-75: a disordered Ge-10 germanate with pcu topology2012Inngår i: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 41, nr 40, s. 12358-12364Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A disordered open-framework germanate, denoted as SU-75, was synthesized under hydrothermal conditions using diethylenetriamine (dien) or alternatively 1,4-diaminobutane (dab) as the structure directing agent (SDA). SU-75 crystallizes in a tetragonal space group I-42d(No. 122) with a= 18.145(3) Å and c= 41.701(9) Å. The three-dimensional (3D) framework is built from Ge10(O,OH)28(Ge10) clusters that are connected following the pcu ( primitive cubic) net topology. SU-75 has 10-, 11- and 12-ring channels along the a- and b-axes and channels with alternating 8-, 10-, 12-, 10-ring openings along the c-axis. The framework exhibits a serious disorder, resulted from two possible connectivities between the units of four Ge 10clusters (4Ge10 unit). The chemical formula of SU-75 is |(H2SDA)2(H2O)n|[Ge10O21(OH)2] (SDA = dien or dab,n= 5–6), determined by combining single crystalsynchrotron X-ray diffraction, thermogravimetric analysis (TGA) and CHN elemental analysis. A superoctahedron is introduced to simplify the description of the connectivity of the Ge10 clusters and to illustrate the disorder. This is also used to compare the structure of SU-75 with those of related Ge10 germanates.

  • 9.
    Inge, A. Ken
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Christensen, Kirsten E.
    Willhammar, Tom
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    A Germanate with a Collapsible Open-Framework2016Inngår i: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 16, nr 12, s. 6967-6973Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A novel open-framework germanate, vertical bar NC2H8 vertical bar vertical bar N2C6H18 vertical bar, [Ge7O14.5F2].4H(2)O denoted SU-65 (SU = Stockholm University), with 24-ring channels and a very low framework density of 8.9 Ge atoms per 1000 angstrom(3) was synthesized under hydro-solvothermal conditions. The framework of SU-65 is built of 5-connected Ge-7 clusters decorating the fee net and is a framework orientation isomer to ASU-16. Half of the 8- and 12-rings in ASU-16 are instead 10-rings in SU-65 due to the different orientations of half of the clusters in the crystal structure. Flexibility of the frameworks is also influenced by the orientation of the clusters. The unique unit cell angle in SU-65 changes upon heating, unlike ASU-16 which only undergoes changes in unit cell lengths. SU-65 undergoes significant structural changes at 180 degrees C in a vacuum, forming SU-65ht. The crystal structure of SU-65ht was investigated by rotation electron diffraction, X-ray powder diffraction, and infrared spectroscopy. Through these techniques it was deduced that SU-65ht has similar clusters, symmetry, and topology as SU-65, but one of the unit cell lengths is shortened by approximately 5 A. This corresponds to a 22% decrease in unit cell volume.

  • 10.
    Inge, A. Ken
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Fahlquist, Henrik
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Willhammar, Tom
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Huang, Yining
    McCusker, Lynne B.
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Solving complex open-framework structures from X-ray powder diffraction by direct-space methods using composite building units2013Inngår i: Journal of applied crystallography, ISSN 0021-8898, E-ISSN 1600-5767, Vol. 46, s. 1094-1104Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The crystal structure of a novel open-framework gallogermanate, SU-66 {|(C6H18N2)(18)(H2O)(32)|[Ga4.8Ge87.2O208]}, has been solved from laboratory X-ray powder diffraction (XPD) data by using a direct-space structure solution algorithm and local structural information obtained from infrared (IR) spectroscopy. IR studies on 18 known germanates revealed that the bands in their IR spectra were characteristic of the different composite building units (CBUs) present in the structures. By comparing the bands corresponding to Ge-O vibrations in the IR spectra of SU-66 with those of the 18 known structures with different CBUs, the CBU of SU-66 could be identified empirically as the Ge-10(O,OH)(27) cluster (Ge-10). The unit cell and space group (extinction symbol P--a; a = 14.963, b = 31.593, c = 18.759 angstrom) were determined initially from the XPD pattern and then confirmed by selected-area electron diffraction. The structure of SU-66 was solved from the XPD data using parallel tempering as implemented in FOX [Favre-Nicolin & Cerny (2002). J. Appl. Cryst. 35, 734-743] by assuming P2(1)ma symmetry and two Ge-10 clusters in the asymmetric unit. Rietveld refinement of the resulting structure using synchrotron XPD data showed the framework structure to be correct and the space group to be Pmma. The framework has extra-large (26-ring) onedimensional channels and a very low framework density of 10.1 Ge/Ga atoms per 1000 angstrom(3). SU-66, with 55 framework atoms in the asymmetric unit, is one of the more complicated framework structures solved from XPD data. Indeed, 98% of the reflections were overlapping in the XPD pattern used for structure solution. Tests on other open-framework germanates (SU-62, SU-65, SU-74, PKU-12 and ITQ-37) for which the XPD data, unit cell, space group and IR spectra were available proved to be equally successful. In a more complex case (SU-72) the combination of FOX and powder charge flipping was required for structure solution.

  • 11.
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Open-Framework Germanates: Synthesis, Structure, and Characterization2012Doktoravhandling, med artikler (Annet vitenskapelig)
    Abstract [en]

    Novel open-framework germanates and open low-dimensional structures were synthesized and characterized. Their crystal structures were solved by single crystal X-ray diffraction or X-ray powder diffraction combined with other techniques. Although related open-framework materials, such as zeolites, are of interest for the ability to selectively accommodate guest species in their rings, pores and channels, germanates are primarily of interest for their unique structural properties. Compared to aluminosilicate-based zeolites, germanium oxides readily form frameworks with extra-large rings and low framework density. The formation of elegant germanate architectures is attributed to the unique Ge-O bond geometries compared to Si-O, and the tendency to form large clusters.

    This thesis is to serve as an introduction to germanate synthesis, structures and characterization. Structures are categorized in accordance to their building units; the Ge7X19 (Ge7), Ge9X25-26 (Ge9) and Ge10X28 (Ge10) (X = O, OH, or F) clusters. Structure determination techniques as well as the characterization techniques used to examine the properties of the materials are presented. While most of the discussed techniques have routinely been used to study crystalline open-frameworks, we introduce the use of infrared spectroscopy for the identification of cluster types, valuable for structure determination by X-ray powder diffraction. Structures and properties of the novel materials ASU-21, SU-62, SU-63, SU-64, SU-65, SU-66, SU-71, SU-72, SU-73, SU-74, SU-75 and SU-JU-14 are described and put into context with previously known structures. The novel structures are all built of the Ge7, Ge9 or Ge10 clusters, and vary from a framework with novel topology to the first open zero-dimensional germanate cavities built of such clusters.

  • 12.
    Inge, Andrew Kentaro
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Christensen, Kirsten
    Guo, Bing
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    SU-65: The Orientation of Five-connected Ge7X19(X = O, OH, F) Clusters in the fee NetManuskript (preprint) (Annet vitenskapelig)
  • 13.
    Inge, Andrew Kentaro
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Huang, Shiliang
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Chen, Hong
    Moraga, Francisca
    Sun, Junliang
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    The Structure of a Complex Open-framework Germanate Obtained by Combining Powder Charge-Flipping and Simulated Annealing2012Inngår i: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 12, nr 10, s. 4853-4860Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A novel open-framework germanate SU-74 containing intersecting 10- and 12-ring channels was prepared by hydrothermal synthesis using 2-methylpentamethylenediamine (MPMD) or 1-(2-aminoethyl)piperazine (AEP) as the organic structure directing agent (SDA). The framework structure of SU-74-MPMD was solved from X-ray powder diffraction (XRPD) data using powder charge-flipping (pCF). The guest species H2MPMD2+, NH4+ cations and water molecules were located in the voids using real-space simulated annealing. SU-74-MPMD contains 51 non-hydrogen atoms in its asymmetric unit and is one of the most complex framework structures solved by XRPD. The structure of SU-74-AEP was solved by single crystal synchrotron X-ray diffraction. SU-74-MPMD and SU-74-AEP have the same framework structure. The location of the NH4+ cations in both structures is similar, while the positions of the SDAs in the pores are different. SU-74 follows the fcu-11-P21/c net. The underlying topology of SU-74 is compared to those of other Ge10 structures containing additional GeO4 tetrahedra. The presence of additional tetrahedra can significantly affect the framework topology through the addition of edges between the Ge10 nodes.

  • 14.
    Inge, Andrew Kentaro
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK). Christian-Albrechts-Universität zu Kiel, Germany.
    Köppen, Milan
    Su, Jie
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Feyand, Mark
    Xu, Hongyi
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    O'Keeffe, Michael
    Stock, Norbert
    Unprecedented Topological Complexity in a Metal-Organic Framework Constructed from Simple Building Units2016Inngår i: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 138, nr 6, s. 1970-1976Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A bismuth-based metal-organic framework (MOP), [Bi(BTC)(H2O)]center dot 2H(2)O center dot MeOH denoted CAU-17, was synthesized and found to have an exceptionally complicated structure with helical Bi-O rods cross-linked by 1,3,5-benzenetricarboxylate (BTC3-) ligands. Five crystallographically independent 1D channels including two hexagonal channels, two rectangular channels, and one triangular channel have accessible diameters of 9.6, 9.6, 3.6, 3.6, and 3.4 angstrom, respectively. The structure is further complicated by twinning. Rod-incorporated MOF structures typically have underlying nets with only one unique node and three or four unique edges. In contrast, topological analysis of CAU-17 revealed unprecedented complexity for a MOF structure with 54 unique nodes and 135 edges. The complexity originates from the rod packing and the rods themselves, which are related to aperiodic helices.

  • 15.
    Inge, Andrew Kentaro
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Peskov, Maxim V.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Sun, Junliang
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    SU-62: Synthesis and Structure Investigation of a Germanate with a Novel Three-Dimensional Net and Interconnected 10- and 14-Ring Channels2012Inngår i: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 12, nr 1, s. 369-375Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A novel 3D open-framework germanate, vertical bar N(2)C(4)H(14)vertical bar(4) [Ge(20)O(41)(OH)(6)]center dot 3H(2)O (SU-62), was prepared from hydrothermal synthesis using 1,4-diaminobutane as the organic structure directing agent (SDA). The crystal structure was solved by single crystal X-ray diffraction. The framework is built from Ge(10)(O,OH)(27) (Ge(10)) secondary building units and exhibits an irregular three-dimensional channel system encircled by 10- and 14-rings. The framework of SU-62 has an underlying topology that follows a novel five-coordinated svh-5-I4(1)/amd net, while the pores follow the tsi net. The thermal behavior of SU-62 was studied by thermogravimetric (TG) analysis and in situ X-ray diffraction (XRPD). Crystallographic data: orthorhombic, space group Fdd2, unit cell parameters a = 15.297(3) angstrom, b = 53.58(1) angstrom, c = 14.422(3) angstrom, V = 11821(4) angstrom(3), Z = 8.

  • 16.
    Inge, Andrew Kentaro
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Sun, Junliang
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Moraga, Francisca
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Guo, Bing
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Three Low-Dimensional Open-Germanates Derived from the 4^4 NetInngår i: CrystEngComm, ISSN 1466-8033, E-ISSN 1466-8033Artikkel i tidsskrift (Fagfellevurdert)
  • 17.
    Inge, Andrew Kentaro
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Willhammar, Tom
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    McCusker, Lynne
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    SU-66: An Open-framework Gallogermanate with 26-ringchannels Solved by Combining Infrared Spectroscopy, ElectronDiffraction and X-ray Powder DiffractionManuskript (preprint) (Annet vitenskapelig)
  • 18.
    Inge, Andrew Kentaro
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Open-Framework Germanates and Related Materials2013Inngår i: Nanoporous Materials: Synthesis and Applications, London: Taylor & Francis Group, 2013Kapittel i bok, del av antologi (Annet vitenskapelig)
  • 19. Koeppen, Milan
    et al.
    Meyer, Vanessa
    Ångström, Jonas
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Stock, Norbert
    Solvent-Dependent Formation of Three New Bi-Metal-Organic Frameworks Using a Tetracarboxylic Acid2018Inngår i: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 18, nr 7, s. 4060-4067Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Systematic solvent screening using high-throughput solvothermal syntheses with bismuth nitrate pentahydrate and 1,2,4,5-tetrakis-(4-carboxyphenyl)benzene (H4TCPB) led to three new porous Bi-metal-organic frameworks [Bi-2(H2TCPB)(TCPB)(H2O)(2)]center dot xH(2)O (CAU-31), (NH2(CH3)(2) [Bi(TCPB)(H2O)]center dot xH(2)O (CAU-32), and [Bi-4(O)(2)(OH)(2)(H2TCPB)(TCPB)(H2O)(2)]center dot xH(2)O (CAU-33). Compounds CAU-31, -32, and -33 were synthesized in CH3OH, CH3OH/DMF, and DMF/toluene, respectively. The crystal structures were determined using electron diffraction and single-crystal X-ray diffraction in combination with the Rietveld method. The structures of CAU-31 and CAU-32 are composed of isolated Bi3+ ions as the inorganic building unit (IBU), which are connected by the linker ions to form a layered structure with inclined interpenetration and a three-dimensional anionic network, respectively. The IBU of CAU-33 consists of infinite bismuth-oxo rods forming a three-dimensional network by connection of the organic linkers. For CAU-33 structural flexibility was observed, and two phases denoted alpha- and beta-CAU-33 could be isolated.

  • 20. Krüger, Martin
    et al.
    Albat, Martin
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Stock, Norbert
    Investigation of the effect of polar functional groups on the crystal structures of indium MOFs2017Inngår i: CrystEngComm, ISSN 1466-8033, E-ISSN 1466-8033, Vol. 19, nr 31, s. 4622-4628Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Three new In-MOFs with -NH2 and/or -NO2 functionalities are reported using 2-amino-(H2BDC-NH2), 2-nitro-(H2BDC-NO2) and 2-amino-5-nitroterephthalic acid (H2BDC-NH2/NO2). Their structures were determined from single crystal X-ray diffraction data. The structure of the first In-MOF of composition [In(BDC-NH3)(BDC-NH2)] center dot 1.6DMF center dot 1.9H(2)O (In-BDC-NH2;DMF is dimethylformamide; the space group is P6(2)22, a = b = 14.738(2) angstrom and c = 12.257(3) angstrom) is built up by two interpenetrating nets of InOB polyhedra interconnected by BDC-NH2 2-ions to form a framework with qtz topology. Charge balance is accomplished by partial protonation of the amino group, which was confirmed by IR spectroscopy. The interpenetration leads to a decrease of the pore dimension (4.4 angstrom in diameter). Thermogravimetric analysis revealed stability up to 300 degrees C. Replacement of H2BDC-NH2 by H2BDC-NO2 in the reaction mixture led to the iso-reticular MOF containing no -NO2 groups but exclusively un- and amino-functionalized linkers. Hence an indium mediated reduction of the H2BDC-NO2 linker molecule during solvothermal synthesis has occurred. The use of H2BDC-NH2/NO2 under exactly the same reaction conditions did not result in the formation of a MOF, but by changing the synthesis parameters, a new -NH2/-NO2 bifunctionalised In-MOF of composition (DMA)(2).In-3.mu(3)-O)(BDC-NH2/NO2) 4.5] center dot DMF (DMA is dimethylammonium), denoted In-BDC-NH2/NO2, was obtained. The crystal morphology can be altered from cubic to truncated octahedral crystals by varying the DMF/ethanol volume ratio during synthesis. The compound crystallises in the cubic space group I43m, a = 24.8947(1) angstrom, and the framework contains trinuclear {In-3.mu(3)-O)} clusters which are interlinked by the BDC-NH2/NO2 2-ions to form super-tetrahedra. Four face-sharing super-tetrahedra form ultra-tetrahedra which are connected to form the final cubic framework with an ncb topology and isolated inaccessible pores.

  • 21. Krüger, Martin
    et al.
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Reinsch, Helge
    Li, Yuan-Han
    Wahiduzzaman, Mohammad
    Lin, Chia-Her
    Wang, Sue-Lein
    Maurin, Guillaume
    Stock, Norbert
    Polymorphous Al-MOFs Based on V-Shaped Linker Molecules: Synthesis, Properties, and in Situ Investigation of Their Crystallization2017Inngår i: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 56, nr 10, s. 5851-5862Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The in situ and systematic high-throughput investigation of the system Al3+/4,4'-benzophenonedicarboxylic acid (H2BPDC)/DMF/H2O in the presence of various additives was carried out, and a new Al-MOF of composition [Al(OH)(BPDC)], denoted as CAU-21-BPDC, was obtained. Its crystal structure was determined from single-crystal X-ray diffraction data (space group I422, a = b = 17.2528(7) angstrom, c = 23.864(1) angstrom). The structure is built up by octanuclear rings of cis corner-sharing AlO6 polyhedra forming the inorganic building unit (IBU). These {Al8O8} IBUs are arranged in a bcu packing and connected via BPDC2(-) ions in a way that each IBU is linked via two linker molecules to each of the eight adjacent IBUs. Thus, accessible, one-dimensional modulated pores with a diameter between 3.6 and 6.5 angstrom are formed. In addition, tetrahedral cavities are formed by the BPDC2(-) linker molecules. The framework of CAU-21-BPDC is polymorphous with that of CAU-8-BPDC, which contains one-dimensional chains of trans corner-sharing AlO6 polyhedra connected by BPDC2(-) ions. Replacing H2BPDC by 4,4'-oxydibenzoic acid (H2ODB), which contains an oxygen atom between the phenyl rings instead of a keto group, leads to the synthesis of Al-MOFs isoreticular with CAU-8-BPDC and CAU-21-BPDC. In addition, a coordination polymer, [Al(HODB)2(OH)], was discovered and structurally characterized. The structure of CAU-8-ODB was refined from powder X-ray diffraction data, while a Pawley refinement was carried out for CAU-21-ODB to determine the lattice parameters and confirm phase purity. The structure of CAU-21-ODB was confirmed using density functional theory (DFT) calculations. A thorough characterization shows that the CAU-8 and CAU-21-type structures are stable up to 350 and 300 degrees C in air, respectively, almost independent of the linker molecules incorporated. The former MOFs are porous toward N-2 and CO2, while the latter only adsorb CO2.

  • 22. Krüger, Martin
    et al.
    Reinsch, Helge
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Stock, Norbert
    Effect of partial linker fluorination and linker extension on structure and properties of the Al-MOF CAU-102017Inngår i: Microporous and Mesoporous Materials, ISSN 1387-1811, E-ISSN 1873-3093, Vol. 249, s. 128-136Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The systematic investigation of the solvothermal system Al3+/5-fluoroisophthalic acid (H(2)mBDC-5F)/isophthalic acid (H(2)mBDC)/DMF/H2O through a mixed-linker approach led to new mixed-linker CAU-10 derivatives containing 11, 28 and 44% of fluorinated linker molecules (denoted as CAU-10-H/F-11, CAU-10-H/F-28 and CAU-10-H/F-44, respectively), as determined by NMR spectroscopy. The crystal structure of CAU-10-H/F-28 was determined using the Rietveld method (space group 14(1)md, a = b = 21.3075(5), c = 10.7101(3) angstrom). The structure is built up by helical chains composed of cis corner-sharing AlO6 polyhedra. Each of these helices is interconnected to four adjacent helices with alternating rotational orientation through the carboxylate groups of mBDC(2-) linker molecules. Thus, accessible, square-shaped channels are formed. Sorption measurements revealed a high dependency of the adsorbed amount of gas on the degree of fluorination. With increasing fluorination, the total uptake decreases in N-2, H-2 and H2O sorption experiments and the hydrophobic character of the pores increases. In addition, an extended CAU-10 derivative, CAU-10-HTATB, was discovered using the tricarboxylic acid 4,4',4-s-triazine-2,4,6-triyl-tribenzoic acid (H(3)TATB) during the high-throughput investigation of the system Al3+/H(3)TATB/DMF/H2O. This new MOF, which was denoted CAU-10-HTATB, was thoroughly characterized using IR spectroscopy, thermogravimetric and elemental analysis, temperature dependent powder X-ray diffraction (PXRD) and sorption measurements. Although the compound is thermally stable up to 400 degrees C according to temperature-dependent PXRD measurements, it is not porous towards N2 molecules. The structure of CAU-10-HTATB could be also refined from PXRD data using the Rietveld method (space group l4(1)/a, a = b = 36.438 (1), c = 10.9373 (9) angstrom).

  • 23. Köppen, Milan
    et al.
    Dhakshinamoorthy, Amarajothi
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK). Christian‐Albrechts‐Universität zu Kiel, Germany.
    Cheung, Ocean
    Ångström, Jonas
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Mayer, Peter
    Stock, Norbert
    Synthesis, Transformation, Catalysis, and Gas Sorption Investigations on the Bismuth Metal-Organic Framework CAU-172018Inngår i: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-1948, nr 30, s. 3496-3503Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Very few microporous bismuth metal-organic frameworks have been discovered to date. Of these, no detailed experimental characterization of the synthesis and properties have been reported until now for the only one which can be prepared from inexpensive starting materials: CAU-17 [Bi(BTC)(H2O)], with H3BTC = trimesic acid. In-situ powder X-ray diffraction during solvothermal synthesis of CAU-17 revealed that it crystallizes rapidly within 2 minutes, and if the reaction is not stopped, the MOF transforms into a nonporous dense purely inorganic material within one hour, revealing that CAU-17 is a crystalline intermediate phase. Synthesis scale-up employing more concentrated reaction mixtures resulted in another Bi trimesate of composition [Bi(HBTC)(NO3)(MeOH)]MeOH, which structurally decomposes upon storage under ambient conditions. Sorption experiments showed that CAU-17 is microporous with a BET surface area of 530 m(2)/g. As a potential greenhouse gas sorbent, CAU-17 showed high SF6/N-2 and CO2/N-2 selectivity > 31 and 29, respectively. Furthermore, the catalytic activity of CAU-17 was studied in the regioselective ring-opening of styrene oxide by methanol to obtain 2-methoxy-2-phenylethanol, thus demonstrating the existence of coordinatively unsaturated sites in the crystal structure of CAU-17.

  • 24.
    Lee, Bao-Lin
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Kärkäs, Markus D.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Johnston, Eric V.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Inge, Andrew K.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Tran, Lien-Hoa
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Xu, Yunhua
    Hansson, Örjan
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Åkermark, Björn
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Synthesis and characterization of oligonuclear Ru, Co, and Cu oxidation catalysts2010Inngår i: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-1948, nr 34, s. 5462-5470Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    In this work, we report the preparation and crystal structures of three new oligonuclear complexes, Ru-2(bbpmp)(mu-OAc)(3) (4), [Co-2(bbpmp)(mu-OAc)(mu-OMe)](PF6) (5), [Cu-4(Hbbpmp)(2)(mu-OAc)(H2O)(2)](OAc)(PF6)(2) (6) {H(3)bbpmp = 2,6-bis[(2-hydroxybenzyl)-(2-pyridylmethyl)aminomethyl]-4-methylphenol (3)}. The structures of the complexes were determined by single-crystal X-ray diffraction. The oxidation states of ruthenium, cobalt and copper in the complexes are +3, +3 and +2, respectively. In 4 and 5, Ru-III and Co-III are coordinated to four oxygen and two nitrogen atoms in an octahedral geometry, while in 6, Cu-II adopts both octahedral (CuN2O4) and square-pyramidal (CuN2O3) geometry. The potential of the three complexes as oxidation catalysts has been investigated.

  • 25. Lenzen, Dirk
    et al.
    Zhao, Jingjing
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Ernst, Sebastian-Johannes
    Wahiduzzaman, Mohammad
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Fröhlich, Dominik
    Xu, Hongyi
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Bart, Hans-Jörg
    Janiak, Christoph
    Henninger, Stefan
    Maurin, Guillaume
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Stock, Norbert
    A metal-organic framework for efficient water-based ultra-low-temperature-driven cooling2019Inngår i: Nature Communications, ISSN 2041-1723, E-ISSN 2041-1723, Vol. 10, artikkel-id 3025Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Efficient use of energy for cooling applications is a very important and challenging field in science. Ultra-low temperature actuated (T-driving< 80 degrees C) adsorption-driven chillers (ADCs) with water as the cooling agent are one environmentally benign option. The nanoscale metal-organic framework [Al(OH)(C6H2O4S)] denoted CAU-23 was discovered that possess favorable properties, including water adsorption capacity of 0.37 g(H2O)/g(sorbent) around p/p(0 )= 0.3 and cycling stability of at least 5000 cycles. Most importantly the material has a driving temperature down to 60 degrees C, which allows for the exploitation of yet mostly unused temperature sources and a more efficient use of energy. These exceptional properties are due to its unique crystal structure, which was unequivocally elucidated by single crystal electron diffraction. Monte Carlo simulations were performed to reveal the water adsorption mechanism at the atomic level. With its green synthesis, CAU-23 is an ideal material to realize ultra-low temperature driven ADC devices.

  • 26.
    Li, Man-Bo
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Posevins, Daniels
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Gustafson, Karl P. J.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Qiu, Youai
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Bäckvall, Jan-E.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Chemodivergent and Diastereoselective Synthesis of gamma-Lactones and gamma-Lactams: A Heterogeneous Palladium-Catalyzed Oxidative Tandem Process2018Inngår i: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 140, nr 44, s. 14604-14608Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A palladium-catalyzed oxidative tandem process of enallenols was accomplished within a homogeneous/heterogeneous catalysis manifold, setting the stage for the highly chemodivergent and diaster-eoselective synthesis of gamma-lactones and gamma-lactams under mild conditions.

  • 27.
    Pascanu, Vlad
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi. University of Zurich, Switzerland.
    González Miera, Greco
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Martín-Matute, Belén
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Metal-Organic Frameworks as Catalysts for Organic Synthesis: A Critical Perspective2019Inngår i: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 141, nr 18, s. 7223-7234Artikkel, forskningsoversikt (Fagfellevurdert)
    Abstract [en]

    Recent advances in organic chemistry and materials chemistry have enabled the porosity of new materials to be accurately controlled on the nanometer scale. In this context, metal-organic frameworks (MOFs) have rapidly become one of the most attractive classes of solid supports currently under investigation in heterogeneous catalysis. Their unprecedented degree of tunability gives MOFs the chance to succeed where others have failed. The past decade has witnessed an exponential growth in the complexity of new structures. MOFs with a variety of topologies and pore sizes show excellent stability across wide ranges of pH and temperature. Even the controlled insertion of defects, to alter the MOF's properties in a predictable manner, has become commonplace. However, research on catalysis with MOFs has been sluggish in catching up with modern trends in organic chemistry. Relevant issues such as enantioselective processes, C-H activation, or olefin metathesis are still rarely discussed. In this Perspective, we highlight meritorious examples that tackle important issues from contemporary organic synthesis, and that provide a fair comparison with existing catalysts. Some of these MOF catalysts already outcompete state-of-the-art homogeneous solutions. For others, improvements may still be required, but they have merit in aiming for the bigger challenge. Furthermore, we also identify some important areas where MOFs are likely to make a difference, by addressing currently unmet needs in catalysis instead of trying to outcompete homogeneous catalysts in areas where they excel. Finally, we strongly advocate for rational design of MOF catalysts, founded on a deep mechanistic understanding of the events taking place inside the pore.

  • 28. Ren, Yansong
    et al.
    Xie, Sheng
    Svensson Grape, Erik
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Ramström, Olof
    Multistimuli-Responsive Enaminitrile Molecular Switches Displaying H+-Induced Aggregate Emission, Metal Ion-Induced Turn-On Fluorescence, and Organogelation Properties2018Inngår i: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 140, nr 42, s. 13640-13643Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Multistimuli-responsive enaminitrile-based configurational switches displaying aggregation-induced emission (AIE), fluorescence turn-on effects, and super gelation properties are presented. The E-isomers dominated (>97%) in neutral/basic solution, and the structures underwent precisely controlled switching around the enamine C=C bond upon addition of acid/base. Specific fluorescence output was observed in response to different external input in the solution and solid states. In response to H+, configurational switching resulted in complete formation of the nonemissive Z-H+-isomers in solution, however displaying deep-blue to blue fluorescence (Phi(F) up to 0.41) in the solid state. In response to Cu-II in the solution state, the E-isomers exhibited intense, turn-on, blue-green fluorescence, which could be turned off by addition of competitive coordination. The acid/base-activated switching, together with the induced AIE-effects, further enabled the accomplishment of a responsive superorganogelator. In nonpolar solvents, a blue-fluorescent supramolecular gel was formed upon addition of acid to the E-isomer suspension. The gelation could be reversed by addition of base, and the overall, reversible process could be repeated at least five cycles.

  • 29. Spekreijse, Jurjen
    et al.
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Öhrström, Lars
    Lignin Based Molecular Materials - a Zinc Vanillate with a Hydrogen Bonded 4-and 8-connected Net with a New Topology2018Inngår i: Israel Journal of Chemistry, ISSN 0021-2148, Vol. 58, nr 9-10, s. 1127-1130Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Vanillic acid, C8H8O4, is a possible product from a future biorefinery with lignin as raw material. Two coordination compounds with this ligand in two different protonation states were prepared: 1 [Zn(C8H7O4)(2)(H2O)(2)] and 2 [Co-2(C8H6O4)(2)(H2O)(6)] 2H(2)O. Both compounds form extended 3D structures with strong hydrogen bonds. A high symmetry 8- and 4-connected network topology, jus, is found in 1. The dinuclear coordination entity in 2 hints at a potentially useful SBU for MOF synthesis from lignin based bridging ligands.

  • 30.
    Tang, Liqiu
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Ren, Xiaoyan
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Willhammar, Tom
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Gruner, Daniel
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Yu, Jihong
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    A Stacking Faults-Containing Silicogermanate with 24-Ring Channels and Unbranched Zweier Silica Double Chains2012Inngår i: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 12, nr 7, s. 3714-3719Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A novel open-framework silicogermanate SU-JU-14 (Stockholm University-Jilin University-Number 14), vertical bar NH3CH2CH2NH3 vertical bar(3)[Ge6.40Si0.60O15(OH)](2)[Ge0.73Si3.27O8], was synthesized by using ethylenediamine as the structure-directing agent under solvothermal conditions. Single-crystal structure analysis reveals that the crystal structure of SU-JU-14 consists of extended 24-ring channels built from [(Ge,Si)(7)O12O6/2(OH)](3-) [(Ge,Si)(7)] clusters and unbranched zweier silica double chains [Ge0.73Si3.27O4O8/2]. Charge neutrality is achieved by diprotonated ethylenediamine guest molecules. The structure consists of stacking faults of layered arrays in two different configurations along the a-axis. SU-JU-14 was characterized by X-ray diffraction, X-ray energy dispersive spectroscopy, scanning electron microscopy, nuclear magnetic resonance, inductively coupled plasma, and thermogravimetric analyses. Crystallographic data: monoclinic, space group C2/c, and unit cell parameters: a = 35.625 (7) angstrom, b = 28.580 (6) angstrom, c = 10.403 (2) angstrom, and beta = 98.30 (3)degrees.

  • 31.
    Tang, Liqiu
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Ren, Xiaoyan
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Willhammar, Tom
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Grüner, Daniel
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Yu, Jihong
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    A Stacking Faults-containing Silicogermanate with 24-ring Channels and Unbranched Zweier Silica Double ChainsInngår i: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505Artikkel i tidsskrift (Fagfellevurdert)
  • 32. Tong, Lianpeng
    et al.
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Duan, Lele
    Wang, Lei
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Sun, Licheng
    Catalytic Water Oxidation by Mononuclear Ru Complexes with an Anionic Ancillary Ligand2013Inngår i: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 52, nr 5, s. 2505-2518Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Mononuclear Ru-based water oxidation catalysts containing anionic ancillary ligands have shown promising catalytic efficiency and intriguing properties. However, their insolubility in water restricts a detailed mechanism investigation. In order to overcome this disadvantage, complexes [Ru-II(bpc)(bpy)OH2](+) (1(+), bpc = 2,2'-bipyridine-6-carboxylate, bpy = 2,2'-bipyridine) and [Ru-II(bpc)(pic)(3)](+) (2(+), pic = 4-picoline) were prepared and fully characterized, which features an anionic tridentate ligand and has enough solubility for spectroscopic study in water. Using Ce-IV as an electron acceptor, both complexes are able to catalyze O-2-evolving reaction with an impressive rate constant. On the basis of the electrochemical and kinetic studies, a water nucleophilic attack pathway was proposed as the dominant catalytic cycle of the catalytic water oxidation by 1(+), within which several intermediates were detected by MS. Meanwhile, an auxiliary pathway that is related to the concentration of Ce-IV was also revealed. The effect of anionic ligand regarding catalytic water oxidation was discussed explicitly in comparison with previously reported mononuclear Ru catalysts carrying neutral tridentate ligands, for example, 2,2':6',2 ''-terpyridine (tpy). When 2(+) was oxidized to the trivalent state, one of its picoline ligands dissociated from the Ru center. The rate constant of picoline dissociation was evaluated from time-resolved UV-vis spectra.

  • 33.
    Vico Solano, Marta
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    González Miera, Greco
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Pascanu, Vlad
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Martín‐Matute, Belén
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Versatile Heterogeneous Palladium Catalysts for Diverse Carbonylation Reactions under Atmospheric Carbon Monoxide Pressure2018Inngår i: ChemCatChem, ISSN 1867-3880, E-ISSN 1867-3899, Vol. 10, nr 5, s. 1089-1095Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Herein, we report a versatile carbonylation protocol using heterogeneous Pd-0 nanoparticles supported on the metal-organic frameworks (MOFs) MIL-88B-NH2 (Fe/Cr). The synthesis of a vast array of carbonyls, which includes amides, esters, carboxylic acids, and -ketoamides, was achieved through mono- and dicarbonylation reactions. The selectivity could be controlled simply by tuning the reaction conditions. Superior activity and selectivity were recorded in some cases compared to that achieved with commercial Pd/C. However, the utility of an elaborate catalyst support is questionable and important reactivity and recyclability issues are discussed.

  • 34.
    Wang, Bin
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Rhauderwiek, Timo
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Xu, Hongyi
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Yang, Taimin
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Huang, Zhehao
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Stock, Norbert
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    A Porous Cobalt Tetraphosphonate Metal-Organic Framework: Accurate Structure and Guest Molecule Location Determined by Continuous-Rotation Electron Diffraction2018Inngår i: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 24, nr 66, s. 17429-17433Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Single-crystal electron diffraction has shown to be powerful for structure determination of nano- and submicron-sized crystals that are too small to be studied by single-crystal X-ray diffraction. However, it has been very challenging to obtain high quality electron diffraction data from beam sensitive crystals such as metal-organic frameworks (MOFs). It is even more difficult to locate guest species in the pores of MOF crystals. Here, we present synthesis of a novel porous cobalt MOF with 1D channels, [Co-2(Ni-H4TPPP)]center dot 2DABCO center dot 6H(2)O, (denoted Co-CAU-36; DABCO=1,4-diazabicyclo[2.2.2]octane), and its structure determination using continuous rotation electron diffraction (cRED) data. By combining a fast hybrid electron detector with low sample temperature (96 K), high resolution (0.83-1.00 angstrom) cRED data could be obtained from eight Co-CAU-36 crystals. Independent structure determinations were conducted using each of the eight cRED datasets. We show that all atoms in the MOF framework could be located. More importantly, we demonstrate for the first time that organic molecules in the pores, which were previously difficult to find, could be located using the cRED data. A comparison of eight independent structure determinations using different datasets shows that structural models differ only on average by 0.03(2) angstrom for the framework atoms and 0.10(6) and 0.16(12) angstrom for DABCO and water molecules, respectively.

  • 35. Wang, Linqin
    et al.
    Zhang, Jinbao
    Liu, Peng
    Xu, Bo
    Zhang, Biaobiao
    Chen, Hong
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Li, Yuanyuan
    Wang, Haoxin
    Cheng, Yi-Bing
    Kloo, Lars
    Sun, Licheng
    Design and synthesis of dopant-free organic hole-transport materials for perovskite solar cells2018Inngår i: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 54, nr 69Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Two novel dopant-free hole-transport materials (HTMs) with spiro[dibenzo[c,h]xanthene-7,9-fluorene] (SDBXF) skeletons were prepared via facile synthesis routes. A power conversion efficiency of 15.9% in perovskite solar cells is attained by using one HTM without dopants, which is much higher than undoped Spiro-OMeTAD-based devices (10.8%). The crystal structures of both new HTMs were systematically investigated to reveal the reasons behind such differences in performance and to indicate the design principles of more advanced HTMs.

  • 36.
    Wang, Yunchen
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Takki, Sofia
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Cheung, Ocean
    Xu, Hongyi
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Wan, Wei
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Öhrström, Lars
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Elucidation of the elusive structure and formula of the active pharmaceutical ingredient bismuth subgallate by continuous rotation electron diffraction2017Inngår i: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 53, nr 52, s. 7018-7021Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Bismuth subgallate has been used in wound and gastrointestinal therapy for over a century. The combination of continuous rotation electron diffraction and sample cooling finally revealed its structure as a coordination polymer. The structure provides insight regarding its formula, poor solubility, acid resistance and previously unreported gas sorption properties.

  • 37. Wöhlbrandt, Stephan
    et al.
    Beyer, Ole
    Reinsch, Helge
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Svensson Grape, Erik
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Lüning, Ulrich
    Stock, Norbert
    Five New Coordination Polymers with a Bifunctional Phosphonate-Sulfonate Linker Molecule2019Inngår i: Zeitschrift für Anorganische und Allgemeines Chemie, ISSN 0044-2313, E-ISSN 1521-3749, Vol. 645, nr 10, s. 732-739Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The bifunctional linker molecule [5-(phosphonomethyl)-2,4-bis(sulfonomethyl)phenyl]methanesulfonic acid (HO3S-CH2)(3)-C6H2-CH2PO3H2 (abbreviated as H(5)L4) was employed in systematic high-throughput investigations in order to discover new coordination polymers (CPs). Employing 27 metal salts of 17 different metals in this investigation, five new compounds [Mg-2(HL4)(H2O)(6)] (1), [Pb-4(L4)(OH)(3)] (2), [Ba-2(H(2)L4)(OH)(H2O)] (3), [Ba-2(HL4)(H2O)(4)] (4), and [Cd-2,Cd-5(L4)(H2O)(7)] (5) were discovered and their crystal structures were determined. In all compounds, the sulfonate and phosphonate groups could not be resolved since the P and S atoms are statistically occupying the atom site with a ratio of 0.25 to 0.75. This is reflected in the P-O and S-O bond lengths. Four of the structures were determined from single-crystal X-ray diffraction data, whereas the structure of 4 was solved ab initio from powder data using real-space methods and refined using Rietveld methods.

  • 38.
    Xu, Hongyi
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Yang, Taimin
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Waitschat, Steve
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Stock, Norbert
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Electron Crystallography Method for Rapid and Accurate Structure Determination of Small Organic MoleculesManuskript (preprint) (Annet vitenskapelig)
  • 39.
    Yuan, Ning
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK). Swedish University of Agricultural Sciences, Sweden.
    Majeed, Maitham H.
    Bajnóczi, Éva G.
    Persson, Axel R.
    Wallenberg, L. Reine
    Ken Inge, Andrew
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Heidenreich, Niclas
    Stock, Norbert
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Wendt, Ola F.
    Persson, Ingmar
    In Situ XAS Study of the Local Structure and Oxidation State Evolutions of Palladium in a Reduced Graphene Oxide Supported Pd(II) Carbene Complex during an Undirected C−H Acetoxylation Reaction2019Inngår i: Catalysis Science & Technology, ISSN 2044-4753, E-ISSN 2044-4761, Vol. 9, nr 8, s. 2025-2031Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    In situ X-ray absorption spectroscopy (XAS) investigations have been performed to provide insights into the reaction mechanism of a palladium(II) catalyzed undirected C–H acetoxylation reaction in the presence of an oxidant. A Pd(II) N-heterocyclic carbene complex p-stacked onto reduced graphene oxide (rGO) was used as catalyst. The Pd speciation during the catalytic process was examined by XAS, which revealed a possible mechanism over the course of the reaction. Pd(II) complexes in the as-synthesized catalyst first go through a gradual ligand substitution where chloride ions bound to Pd(II) are replaced by other ligands with a bond distance to Pd corresponding to carbon, nitrogen and/or oxygen (L). Parallel to this the mean oxidation state of Pd increases indicating the formation of Pd(IV) species. At a later stage, a fraction of the Pd complexes start to slowly transform into Pd nanoclusters. The mean average oxidation state of Pd decreases to the initial state at the end of the experiment which means that comparable amounts of Pd(0) and Pd(IV) are present. These observations from heterogeneous catalysis are in good agreement with its homogeneous analog and they support a Pd(II)-Pd(IV)-Pd(II) reaction mechanism.

  • 40.
    Yuan, Ning
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK). Swedish University of Agricultural Sciences, Sweden.
    Pascanu, Vlad
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Huang, Zhehao
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Heidenreich, Niclas
    Leubner, Sebastian
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Gaar, Jakob
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Stock, Norbert
    Persson, Ingmar
    Martín-Matute, Belén
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Probing the active catalytic species generated from Pd(II)@MIL-101-NH2 in Heck coupling reactions: An operando X-ray absorption spectroscopy studyArtikkel i tidsskrift (Fagfellevurdert)
  • 41.
    Yuan, Ning
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK). Swedish University of Agricultural Sciences, Sweden.
    Pascanu, Vlad
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Huang, Zhehao
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Valiente, Alejandro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Heidenreich, Niclas
    Leubner, Sebastian
    Inge, Andrew Kentaro
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Gaar, Jakob
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Stock, Norbert
    Persson, Ingmar
    Martín-Matute, Belén
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
    Zou, Xiaodong
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Probing the Evolution of Palladium Species in Pd@MOF Catalysts during the Heck Coupling Reaction: An Operando X-ray Absorption Spectroscopy Study2018Inngår i: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 140, nr 26, s. 8206-8217Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The mechanism of the Heck C-C coupling reaction catalyzed by Pd@MOFs has been investigated using operando X-ray absorption spectroscopy (XAS) and powder X-ray diffraction (PXRD) combined with transmission electron microscopy (TEM) analysis and nuclear magnetic resonance (H-1 NMR) kinetic studies. A custom-made reaction cell was used, allowing operando PXRD and XAS data collection using high-energy synchrotron radiation. By analyzing the XAS data in combination with ex situ studies, the evolution of the palladium species is followed from the as-synthesized to its deactivated form. An adaptive reaction mechanism is proposed. Mononuclear Pd(II) complexes are found to be the dominant active species at the beginning of the reaction, which then gradually transform into Pd nanoclusters with 13-20 Pd atoms on average in later catalytic turnovers. Consumption of available reagent and substrate leads to coordination of Cl- ions to their surfaces, which causes the poisoning of the active sites. By understanding the deactivation process, it was possible to tune the reaction conditions and prolong the lifetime of the catalyst.

  • 42. Zhang, Kaiheng
    et al.
    Deiana, Luca
    Svensson Grape, Erik
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Inge, A. Ken
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Córdova, Armando
    Catalytic Enantioselective Synthesis of Bicyclic Lactam N,S-Acetals in One Pot by Cascade Transformations2019Inngår i: European Journal of Organic Chemistry, ISSN 1434-193X, E-ISSN 1099-0690, nr 29, s. 4649-4657Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A versatile strategy for the enantioselective synthesis of bicyclic lactam N,S-acetals by one-pot cascade transformations is disclosed. The transformation of readily available substrates is promoted by chiral amines and creates bicyclic or tricyclic lactam N,S-acetals with high chemo- and stereoselectivity (up to > 99.5:0.5 dr and > 99 % ee) in one-pot operations.

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