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  • 1.
    Amann, Peter
    et al.
    Stockholm University, Faculty of Science, Department of Physics.
    Degerman, David
    Stockholm University, Faculty of Science, Department of Physics.
    Lee, Ming-Tao
    Alexander, John D.
    Stockholm University, Faculty of Science, Department of Physics.
    Shipilin, Mikhail
    Stockholm University, Faculty of Science, Department of Physics.
    Wang, Hsin-Yi
    Stockholm University, Faculty of Science, Department of Physics.
    Cavalca, Filippo
    Weston, Matthew
    Stockholm University, Faculty of Science, Department of Physics.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Blom, Mikael
    Stockholm University, Faculty of Science, Department of Physics.
    Björkhage, Mikael
    Stockholm University, Faculty of Science, Department of Physics.
    Löfgren, Patrik
    Stockholm University, Faculty of Science, Department of Physics.
    Schlueter, Christoph
    Drube, Wofgang
    Lömker, Patrick
    Ederer, Katrin
    Noei, Heshmat
    Zehetner, Johann
    Wentzel, Henrik
    Åhlund, John
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics.
    A dedicated photoelectron spectroscopy instrument for studies of catalytic reactions at pressures exceeding 1 barManuscript (preprint) (Other academic)
    Abstract [en]

    Here, we present a new high-pressure x-ray photoelectron spectroscopy system dedicated to probing catalytic reactions under realistic conditions at pressures exceeding 1 bar. The instrument builds around the concept of a “virtual cell” in which a gasflow is directed onto the sample surface creating a local high pressure on top of the sample. This allows the instrument to maintain a low pressure of a few mbars in the main chamber, while simultaneously keeping a local pressure of around 1 bar. Synchrotron radiation based grazing incidence photoemission within ± 5° is used to enhance the surface sensitivity in the experiment. The aperture, separating the high-pressure region from the differential pumping of the electron spectrometer, consists of multiple, evenly spaced, mm sized holes matching the footprint of the x-ray beam on the sample surface. As the photo-emitted electrons are subject to strong scattering in the gas phase and the resulting signal is therefore highly dependent on the sample to aperture distance, the latter is controlled with high precision using a fully integrated manipulator that allows for sample movement with step sizes of 10 nm between 0 and –5 mm with very low vibrational amplitude. The instrumental features allows acquisition of metallic bulk spectra at He pressures up to 2.5 bar and also allows for following C1s spectra under realistic gas mixtures of CO + H2with various temperatures up to 500°C. This capability opens for studies of catalytic reactions in operandi.

  • 2. Beye, M.
    et al.
    Anniyev, T.
    Coffee, R.
    Dell'Angela, M.
    Foehlisch, A.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Katayama, T.
    Kaya, S.
    Krupin, O.
    Mogelhoj, A.
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Nordlund, D.
    Norskov, J. K.
    Öberg, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Ogasawara, H.
    Pettersson, Lars G. M.
    Stockholm University, Faculty of Science, Department of Physics.
    Schlotter, W. F.
    Sellberg, Jonas
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Sorgenfrei, F.
    Turner, J. J.
    Wolf, M.
    Wurth, W.
    Öström, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Selective Ultrafast Probing of Transient Hot Chemisorbed and Precursor States of CO on Ru(0001)2013In: Physical Review Letters, ISSN 0031-9007, E-ISSN 1079-7114, Vol. 110, no 18, article id 186101Article in journal (Refereed)
    Abstract [en]

    We have studied the femtosecond dynamics following optical laser excitation of CO adsorbed on a Ru surface by monitoring changes in the occupied and unoccupied electronic structure using ultrafast soft x-ray absorption and emission. We recently reported [M. Dell'Angela et al. Science 339, 1302 (2013)] a phonon-mediated transition into a weakly adsorbed precursor state occurring on a time scale of >2 ps prior to desorption. Here we focus on processes within the first picosecond after laser excitation and show that the metal-adsorbate coordination is initially increased due to hot-electron-driven vibrational excitations. This process is faster than, but occurs in parallel with, the transition into the precursor state. With resonant x-ray emission spectroscopy, we probe each of these states selectively and determine the respective transient populations depending on optical laser fluence. Ab initio molecular dynamics simulations of CO adsorbed on Ru(0001) were performed at 1500 and 3000 K providing insight into the desorption process.

  • 3. Beye, Martin
    et al.
    Öberg, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Xin, Hongliang
    Dakovski, Georgi L.
    Dell'Angela, Martina
    Föhlisch, Alexander
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Hantschmann, Markus
    Hieke, Florian
    Kaya, Sarp
    Kuehn, Danilo
    LaRue, Jerry
    Mercurio, Giuseppe
    Minitti, Michael P.
    Mitra, Ankush
    Stockholm University, Faculty of Science, Department of Physics.
    Moeller, Stefan P.
    Ng, May Ling
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, United States.
    Nordlund, Dennis
    Norskov, Jens
    Östrom, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Ogasawara, Hirohito
    Persson, Mats
    Schlotter, William F.
    Sellberg, Jonas A.
    Stockholm University, Faculty of Science, Department of Physics. KTH Royal Institute of Technology, Sweden; SLAC National Accelerator Laboratory, United States.
    Wolf, Martin
    Abild-Pedersen, Frank
    Pettersson, Lars G. M.
    Stockholm University, Faculty of Science, Department of Physics.
    Wurth, Wilfried
    Chemical Bond Activation Observed with an X-ray Laser2016In: Journal of Physical Chemistry Letters, ISSN 1948-7185, E-ISSN 1948-7185, Vol. 7, no 18, p. 3647-3651Article in journal (Refereed)
    Abstract [en]

    The concept of bonding and antibonding orbitals is fundamental in chemistry. The population of those orbitals and the energetic difference between the two reflect the strength of the bonding interaction. Weakening the bond is expected to reduce this energetic splitting, but the transient character of bond-activation has so far prohibited direct experimental access. Here we apply time-resolved soft X-ray spectroscopy at a free electron laser to directly observe the decreased bonding antibonding splitting following bond-activation using an ultrashort optical laser pulse.

  • 4.
    Degerman, David
    et al.
    Stockholm University, Faculty of Science, Department of Physics.
    Amann, Peter
    Stockholm University, Faculty of Science, Department of Physics.
    Shilpilin, Mikhail
    Stockholm University, Faculty of Science, Department of Physics.
    Wang, Hsin-Yi
    Stockholm University, Faculty of Science, Department of Physics.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Lömker, Patrick
    Heshmat, Noei
    Schlueter, Christoph
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics.
    Surface adsorbates during CO2 Hydrogenation on Rh(111) probed in-situ by x-ray photoelectron spectroscopy at 150 mbarManuscript (preprint) (Other academic)
    Abstract [en]

    The catalytic CO2 hydrogenation reaction was examined in situ by High Pressure X-ray Photoelectron Spectroscopy (HP-XPS) at 150 mbar and between 150 and 350°C. The results indicate two temperature regimes; the first one with temperature dependent desorption of carbon species between 150°C and 200°C. The second temperature regime is between 250 and 350 °C. In this interval, the carbon species are formed and immediately reacted away, resulting in a lower temperature dependence on surface coverage. The XPS coverage calculations and the component analysis indicate that water is the most abundant surface adsorbate, and that CHx fragments and CO are the most abundant carbon species. The hydrogenation state of the CHx species varies with temperature, where higher temperatures result in a larger population of more hydrogenated species.

  • 5. Dell'Angela, M.
    et al.
    Anniyev, T.
    Beye, M.
    Coffee, R.
    Foehlisch, A.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Katayama, T.
    Kaya, S.
    Krupin, O.
    LaRue, J.
    Mogelhoj, A.
    Nordlund, D.
    Norskov, J. K.
    Öberg, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Ogasawara, H.
    Öström, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Pettersson, Lars G. M.
    Stockholm University, Faculty of Science, Department of Physics.
    Schlotter, W. F.
    Sellberg, Jonas A.
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Sorgenfrei, F.
    Turner, J. J.
    Wolf, M.
    Wurth, W.
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Real-Time Observation of Surface Bond Breaking with an X-ray Laser2013In: Science, ISSN 0036-8075, E-ISSN 1095-9203, Vol. 339, no 6125, p. 1302-1305Article in journal (Refereed)
    Abstract [en]

    We used the Linac Coherent Light Source free-electron x-ray laser to probe the electronic structure of CO molecules as their chemisorption state on Ru(0001) changes upon exciting the substrate by using a femtosecond optical laser pulse. We observed electronic structure changes that are consistent with a weakening of the CO interaction with the substrate but without notable desorption. A large fraction of the molecules (30%) was trapped in a transient precursor state that would precede desorption. We calculated the free energy of the molecule as a function of the desorption reaction coordinate using density functional theory, including van der Waals interactions. Two distinct adsorption wells-chemisorbed and precursor state separated by an entropy barrier-explain the anomalously high prefactors often observed in desorption of molecules from metals.

  • 6. Dell'Angela, M.
    et al.
    Anniyev, T.
    Beye, M.
    Coffee, R.
    Foehlisch, A.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Kaya, S.
    Katayama, T.
    Krupin, O.
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics. SUNCAT Center for Interface Science and Catalysis, USA; SLAC National Accelerator Laboratory, USA.
    Nordlund, D.
    Schlotter, W. F.
    Sellberg, Jonas A.
    Stockholm University, Faculty of Science, Department of Physics. SUNCAT Center for Interface Science and Catalysis, USA.
    Sorgenfrei, F.
    Turner, J. J.
    Öström, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Ogasawara, H.
    Wolf, M.
    Wurth, W.
    Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer2015In: structural dynamics us, ISSN 2329-7778, Vol. 2, no 2, article id 025101Article in journal (Refereed)
    Abstract [en]

    Vacuum space charge induced kinetic energy shifts of O 1s and Ru 3d core levels in femtosecond soft X-ray photoemission spectra (PES) have been studied at a free electron laser (FEL) for an oxygen layer on Ru(0001). We fully reproduced the measurements by simulating the in-vacuum expansion of the photoelectrons and demonstrate the space charge contribution of the high-order harmonics in the FEL beam. Employing the same analysis for 400 nm pump-X-ray probe PES, we can disentangle the delay dependent Ru 3d energy shifts into effects induced by space charge and by lattice heating from the femtosecond pump pulse.

  • 7.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Bonding and Desorption Mechanismsof CO on Metal Surfaces2012Licentiate thesis, monograph (Other academic)
    Abstract [en]

    I have investigated two different systems CO/Fe(100) and CO/Ru(0001), toobtain new information on the binding and desorption processes. The twodifferent systems have served as a model system, one for a static examination,CO on iron, and for the dynamic case, CO on ruthenium. To perform theseinvestigations, several types of techniques have been used such as, X-rayabsorption spectroscopy, X-ray emission spectroscopy, and femtosecond laserinduced desorption techniques such as two-pulse correlation.

    For the CO/Fe(100) system, we found that the on-top CO “1 phase” canbe described by the Blyholder-Nilsson-Pettersson model. The pre-dissociativephase of CO bound at hollow sites, “3 phase”, can be described in a Dewar-Chatt-Duncanson like picture.

    For the CO/Ru(0001) system, it was found that all our data could be fitted from an empirical friction heat bath model. Moreover, it turned out, thatthere is a strong frictional coupling to the substrate electrons and phonons.

  • 8.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Ultrafast Probing of CO Reactions on Metal Surfaces: Changes in the molecular orbitals during the catalysis process2017Doctoral thesis, comprehensive summary (Other academic)
    Abstract [en]

    This thesis presents experimental studies of three different chemical reaction steps relevant for heterogeneous catalysis: dissociation, desorption, and oxidation. CO on single-crystal metal surfaces was chosen as the model systems.

    X-ray absorption spectroscopy (XAS) and x-ray emission spectroscopy (XES) provide information about the electronic structure, and were performed on CO/Fe to measure both a non-dissociative, and a pre-dissociative state. The measurement on the pre-dissociative state showed a π →  π* excitation, which implies a partly broken internal π bond in the molecule.

    Ultrafast laser-induced reactions were used to examine the dynamic properties of desorption and oxidation. Here CO/Ru and CO/O/Ru were used as model systems. Desorption of CO from a Ru surface involve both hot electrons and phonons. In the case of CO oxidation from CO/O/Ru a pronounced wavelength dependence of the branching ratio between desorption and oxidation was observed. Excitation with 400 nm showed a factor of 3-4 higher selectivity towards oxidation than 800 nm. This was attributed to coupling to transiently excited, non-thermalized electrons.

    Finally, by performing optical pump/x-ray probe XAS and XES changes in the electronic structure during the reaction could be followed, both for desorption and oxidation. In the CO/Ru experiment, two different transient excitation paths were observed, one leading to a precursor state, and one where CO moves into a more highly coordinated site. Using selective excitation in XES, these were shown to coexist on the surface. In the oxidation experiment, probing the reacting species located near the transition state region in an associative catalytic surface reaction was demonstrated for the very first time.

  • 9.
    Gladh, Jörgen
    et al.
    Stockholm University, Faculty of Science, Department of Physics.
    Hansson, Tony
    Stockholm University, Faculty of Science, Department of Physics.
    Öström, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Electron- and phonon-coupling in femtosecond laser-induced desorption of CO from Ru(0001)2013In: Surface Science, ISSN 0039-6028, E-ISSN 1879-2758, Vol. 615, p. 65-71Article in journal (Refereed)
    Abstract [en]

    We studied femtosecond laser-induced desorption of CO from Ru(0001) using intense near-infrared and visible femtosecond laser pulses. We find a pronounced wavelength dependence with a factor 3-4 higher desorption yield at comparable fluence when desorption is induced via 400 nm light, compared to 800 nm and attribute this difference to the difference in penetration depth of the incident light. All our data can be described using empirical friction-modeling to determine the desorption mechanism with the same mechanism for both wavelengths. We find that both hot electrons and phonons contribute to the desorption process.

  • 10.
    Gladh, Jörgen
    et al.
    Stockholm University, Faculty of Science, Department of Physics.
    Öberg, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Li, Jibiao
    Stockholm University, Faculty of Science, Department of Physics.
    Ljungberg, M. P.
    Stockholm University, Faculty of Science, Department of Physics.
    Matsuda, A.
    Stockholm University, Faculty of Science, Department of Physics.
    Ogasawara, H.
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics. Stanford Synchrotron Radiation Lightsource, USA.
    Pettersson, Lars G. M.
    Stockholm University, Faculty of Science, Department of Physics.
    Öström, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    X-ray emission spectroscopy and density functional study of CO/Fe(100)2012In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 136, no 3, article id 034702Article in journal (Refereed)
    Abstract [en]

    We report x-ray emission and absorption spectroscopy studies of the electronic structure of the pre-dissociative alpha(3) phase of CO bound at hollow sites of Fe(100) as well as of the on-top bound species in the high-coverage alpha(1) phase. The analysis is supported by density functional calculations of structures and spectra. The bonding of lying down CO in the hollow site is well described in terms of pi to pi* charge transfer made possible through bonding interaction also at the oxygen in the minority spin-channel. The on-top CO in the mixed, high-coverage alpha(1) phase is found to be tilted due to adsorbate-adsorbate interaction, but still with bonding mainly characteristic of vertical on-top adsorbed CO similar to other transition-metal surfaces.

  • 11.
    Gladh, Jörgen
    et al.
    Stockholm University, Faculty of Science, Department of Physics.
    Öberg, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Pettersson, Lars G. M.
    Stockholm University, Faculty of Science, Department of Physics.
    Öström, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Detection of adsorbate overlayer structural transitions using sum-frequency generation spectroscopy2015In: Surface Science, ISSN 0039-6028, E-ISSN 1879-2758, Vol. 633, p. 77-81Article in journal (Refereed)
    Abstract [en]

    We demonstrate that temperature-programmed vibrational sum-frequency generation (SFG) spectroscopy has a unique sensitivity to certain adsorbate overlayer structural transitions. In the CO stretching vibration of co-adsorbed CO/O(2x1)/Ru(0001) we observe pronounced dips in the spectral intensity as the adsorbate overlayer undergoes structural transitions with temperature. Combining with temperature-programmed desorption (TPD) a more complete picture of temperature-dependent structural transitions is obtained. We extract kinetic parameters from the SFG data and obtain good agreement with TPD when both techniques see the same transition. Infrared-infrared visible SFG is used to determine changes in inter-adsorbate coupling that allow us to experimentally assign the structural transitions. Furthermore, density functional theory calculations of the proposed structures and energetics are performed to verify the experimental assignments.

  • 12. Katayama, T.
    et al.
    Anniyev, T.
    Beye, M.
    Coffee, R.
    Dell'Angela, M.
    Foehlisch, A.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Kaya, S.
    Krupin, O.
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Nordlund, D.
    Schlotter, W. F.
    Sellberg, Jonas A.
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Sorgenfrei, F.
    Turner, J. J.
    Wurth, W.
    Östrom, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Ogasawara, H.
    Ultrafast soft X-ray emission spectroscopy of surface adsorbates using an X-ray free electron laser2013In: Journal of Electron Spectroscopy and Related Phenomena, ISSN 0368-2048, E-ISSN 1873-2526, Vol. 187, p. 9-14Article in journal (Refereed)
    Abstract [en]

    We report on an experimental system designed to probe chemical reactions on solid surfaces on a sub-picosecond timescale using soft X-ray emission spectroscopy at the Linac Coherent Light Source (LCLS) free electron laser (FEL) at the SLAC National Accelerator Laboratory. We analyzed the O 1s X-ray emission spectra recorded from atomic oxygen adsorbed on a Ru(0001) surface at a synchrotron beamline (SSRL, BL13-2) and an FEL beamline (LCLS, SXR). We have demonstrated conditions that provide negligible amount of FEL induced damage of the sample. In addition we show that the setup is capable of tracking the temporal evolution of electronic structure during a surface reaction of submonolayer quantities of CO molecules desorbing from the surface.

  • 13.
    Nilsson, Anders
    et al.
    Stockholm University, Faculty of Science, Department of Physics.
    LaRue, J.
    Öberg, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Ogasawara, H.
    Dell'Angela, M.
    Beye, M.
    Öström, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Nørskov, J. K.
    Wurth, W.
    Abild-Pedersen, F.
    Pettersson, Lars G. M.
    Stockholm University, Faculty of Science, Department of Physics.
    Catalysis in real time using X-ray lasers2017In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 675, p. 145-173Article in journal (Refereed)
    Abstract [en]

    We describe how the unique temporal and spectral characteristics of X-ray free-electron lasers (XFEL) can be utilized to follow chemical transformations in heterogeneous catalysis in real time. We highlight the systematic study of CO oxidation on Ru(0001), which we initiate either using a femtosecond pulse from an optical laser or by activating only the oxygen atoms using a THz pulse. We find that CO is promoted into an entropy-controlled precursor state prior to desorbing when the surface is heated in the absence of oxygen, whereas in the presence of oxygen, CO desorbs directly into the gas phase. We monitor the activation of atomic oxygen explicitly by the reduced split between bonding and antibonding orbitals as the oxygen comes out of the strongly bound hollow position. Applying these novel XFEL techniques to the full oxidation reaction resulted in the surprising observation of a significant fraction of the reactants at the transition state through the electronic signature of the new bond formation.

  • 14.
    Schiros, Theanne
    et al.
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory .
    Andersson, K. J.
    MacNaughton, J.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Matsuda, Akitaka
    Stockholm University, Faculty of Science, Department of Physics. Nagoya University .
    Östrom, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Takahashi, O.
    Pettersson, Lars G. M.
    Stockholm University, Faculty of Science, Department of Physics.
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory .
    Ogasawara, H.
    Unique water-water coordination tailored by a metal surface2013In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 138, no 23, p. 234708-Article in journal (Refereed)
    Abstract [en]

    At low coverage of water on Cu(110), substrate-mediated electrostatics lead to zigzagging chains along [001] as observed with STM [T. Yamada, S. Tamamori, H. Okuyama, and T. Aruga, Anisotropic water chain growth on Cu(110) observed with scanning tunneling microscopy Phys. Rev. Lett. 96, 036105 (2006)]. Using x-ray absorption spectroscopy we find an anomalous low-energy resonance at similar to 533.1 eV which, based on density functional theory spectrum simulations, we assign to an unexpected configuration of water units whose uncoordinated O-H bonds directly face those of their neighbors; this interaction repeats over trough sites with enhanced electron density and is analogous to the case of a hydrated electron.

  • 15. Xin, H.
    et al.
    LaRue, J.
    Öberg, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Beye, M.
    Dell'Angela, M.
    Turner, J. J.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Ng, M. L.
    Sellberg, Jonas A.
    Stockholm University, Faculty of Science, Department of Physics.
    Kaya, S.
    Mercurio, G.
    Hieke, F.
    Nordlund, D.
    Schlotter, W. F.
    Dakovski, G. L.
    Minitti, M. P.
    Foehlisch, A.
    Wolf, M.
    Wurth, W.
    Ogasawara, H.
    Norskov, J. K.
    Östrom, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Pettersson, Lars G. M.
    Stockholm University, Faculty of Science, Department of Physics.
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Abild-Pedersen, E.
    Strong Influence of Coadsorbate Interaction on CO Desorption Dynamics on Ru(0001) Probed by Ultrafast X-Ray Spectroscopy and Ab Initio Simulations2015In: Physical Review Letters, ISSN 0031-9007, E-ISSN 1079-7114, Vol. 114, no 15, article id 156101Article in journal (Refereed)
    Abstract [en]

    We show that coadsorbed oxygen atoms have a dramatic influence on the CO desorption dynamics from Ru(0001). In contrast to the precursor-mediated desorption mechanism on Ru(0001), the presence of surface oxygen modifies the electronic structure of Ru atoms such that CO desorption occurs predominantly via the direct pathway. This phenomenon is directly observed in an ultrafast pump-probe experiment using a soft x-ray free-electron laser to monitor the dynamic evolution of the valence electronic structure of the surface species. This is supported with the potential of mean force along the CO desorption path obtained from density-functional theory calculations. Charge density distribution and frozen-orbital analysis suggest that the oxygen-induced reduction of the Pauli repulsion, and consequent increase of the dative interaction between the CO 5 sigma and the charged Ru atom, is the electronic origin of the distinct desorption dynamics. Ab initio molecular dynamics simulations of CO desorption from Ru(0001) and oxygen-coadsorbed Ru(0001) provide further insights into the surface bond-breaking process.

  • 16.
    Öberg, Henrik
    et al.
    Stockholm University, Faculty of Science, Department of Physics.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Dell'Angela, M.
    Anniyev, T.
    Beye, M.
    Coffee, R.
    Föhlisch, A.
    Katayama, T.
    Kaya, S.
    LaRue, J.
    Mögelhöj, A.
    Nordlund, D.
    Ogasawara, H.
    Schlotter, W. F.
    Sellberg, Jonas A.
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Sorgenfrei, F.
    Turner, J. J.
    Wolf, M.
    Wurth, W.
    Öström, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Nörskov, J. K.
    Pettersson, L. G. M.
    Stockholm University, Faculty of Science, Department of Physics.
    Optical laser-induced CO desorption from Ru(0001) monitored with a free-electron X-ray laser: DFT prediction and X-ray confirmation of a precursor state2015In: Surface Science, ISSN 0039-6028, E-ISSN 1879-2758, Vol. 640, p. 80-88Article in journal (Refereed)
    Abstract [en]

    We present density functional theory modeling of time-resolved optical pump/X-ray spectroscopic probe data of CO desorption from Ru(0001). The BEEF van der Waals functional predicts a weakly bound state as a precursor to desorption. The optical pump leads to a near-instantaneous (<100 fs) increase of the electronic temperature to nearly 7000 K. The temperature evolution and energy transfer between electrons, substrate phonons and adsorbate is described by the two-temperature model and found to equilibrate on a timescale of a few picoseconds to an elevated local temperature of similar to 2000K. Estimating the free energy based on the computed potential of mean force along the desorption path, we find an entropic barrier to desorption (and by time-reversal also to adsorption). This entropic barrier separates the chemisorbed and precursor states, and becomes significant at the elevated temperature of the experiment (similar to 1.4 eV at 2000 K). Experimental pump-probe X-ray absorption/X-ray emission spectroscopy indicates population of a precursor state to desorption upon laser-excitation of the system (Dell'Angela et al., 2013). Computing spectra along the desorption path confirms the picture of a weakly bound transient state arising from ultrafast heating of the metal substrate.

  • 17.
    Öberg, Henrik
    et al.
    Stockholm University, Faculty of Science, Department of Physics.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Marks, Kess
    Stockholm University, Faculty of Science, Department of Physics.
    Ogasawara, H.
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Pettersson, Lars G. M.
    Stockholm University, Faculty of Science, Department of Physics.
    Östrom, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Indication of non-thermal contribution to visible femtosecond laser-induced CO oxidation on Ru(0001)2015In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 143, no 7, article id 074701Article in journal (Refereed)
    Abstract [en]

    We studied CO oxidation on Ru(0001) induced by 400 nm and 800 nm femtosecond laser pulses where we find a branching ratio between CO oxidation and desorption of 1: 9 and 1: 31, respectively, showing higher selectivity towards CO oxidation for the shorter wavelength excitation. Activation energies computed with density functional theory show discrepancies with values extracted from the experiments, indicating both a mixture between different adsorbed phases and importance of non-adiabatic effects on the effective barrier for oxidation. We simulated the reactions using kinetic modeling based on the two-temperature model of laser-induced energy transfer in the substrate combined with a friction model for the coupling to adsorbate vibrations. This model gives an overall good agreement with experiment except for the substantial difference in yield ratio between CO oxidation and desorption at 400 nm and 800 nm. However, including also the initial, non-thermal effect of electrons transiently excited into antibonding states of the O-Ru bond yielded good agreement with all experimental results.

  • 18.
    Öberg, Henrik
    et al.
    Stockholm University, Faculty of Science, Department of Physics.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Pettersson, Lars G M
    Stockholm University, Faculty of Science, Department of Physics.
    Öström, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    CO oxidation on Ru(0001) modeled from first-principles and femtosecond laser measurementsManuscript (preprint) (Other academic)
  • 19.
    Öberg, Henrik
    et al.
    Stockholm University, Faculty of Science, Department of Physics.
    Nestsiarenka, Yuliya
    Stockholm University, Faculty of Science, Department of Physics.
    Matsuda, A.
    Stockholm University, Faculty of Science, Department of Physics.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Hansson, Tony
    Stockholm University, Faculty of Science, Department of Physics.
    Pettersson, Lars G.M.
    Stockholm University, Faculty of Science, Department of Physics.
    Öström, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Adsorption and Cyclotrimerization Kinetics of C2H2 at a Cu(110) Surface2012In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 116, no 17, p. 9550-9560Article in journal (Refereed)
    Abstract [en]

    The kinetics of acetylene adsorption and cyclotrimerization was studied by vibrational sum-frequency generation spectroscopy (SFG) and density functional theory (DFT) calculations. At low temperature, SFG shows two resonances corresponding to acetylene adsorbed in two different sites. Upon heating, two new vibrational resonances appear. We interpret these resonances as being due to C2H2 island formation and adsorbed C4H4, which is the intermediate in the subsequent cyclotrimerization reaction to form benzene. A kinetic model is applied, which allows determination of the relevant activation barriers. The barrier for C2H2 diffusion is determined to be 43 +/- 1 kJ/mol. The activation barrier for formation of the C4H4 intermediate is found to be 84 +/- 6 kJ/mol and the barrier for benzene formation 5 +/- 3 kJ/mol lower. Barriers to diffusion and formation of C4H4 and C6H6 obtained from DFT calculations are in quantitative agreement with the experiments once the locally high coverage in C2H2 islands is included.

  • 20.
    Östrom, Henrik
    et al.
    Stockholm University, Faculty of Science, Department of Physics.
    Öberg, Henrik
    Stockholm University, Faculty of Science, Department of Physics.
    Xin, H.
    Larue, J.
    Beye, M.
    Dell'Angela, M.
    Gladh, Jörgen
    Stockholm University, Faculty of Science, Department of Physics.
    Ng, M. L.
    Sellberg, Jonas A.
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Kaya, S.
    Mercurio, G.
    Nordlund, D.
    Hantschmann, M.
    Hieke, F.
    Kuehn, D.
    Schlotter, W. F.
    Dakovski, G. L.
    Turner, J. J.
    Minitti, M. P.
    Mitra, A.
    Moeller, S. P.
    Foehlisch, A.
    Wolf, M.
    Wurth, W.
    Persson, M.
    Norskov, J. K.
    Abild-Pedersen, F.
    Ogasawara, H.
    Pettersson, Lars G. M.
    Stockholm University, Faculty of Science, Department of Physics.
    Nilsson, Anders
    Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, USA.
    Probing the transition state region in catalytic CO oxidation on Ru2015In: Science, ISSN 0036-8075, E-ISSN 1095-9203, Vol. 347, no 6225, p. 978-982Article in journal (Refereed)
    Abstract [en]

    Femtosecond x-ray laser pulses are used to probe the carbon monoxide (CO) oxidation reaction on ruthenium (Ru) initiated by an optical laser pulse. On a time scale of a few hundred femtoseconds, the optical laser pulse excites motions of CO and oxygen (O) on the surface, allowing the reactants to collide, and, with a transient close to a picosecond (ps), new electronic states appear in the OK-edge x-ray absorption spectrum. Density functional theory calculations indicate that these result from changes in the adsorption site and bond formation between CO and O with a distribution of OC-O bond lengths close to the transition state (TS). After 1 ps, 10% of the CO populate the TS region, which is consistent with predictions based on a quantum oscillator model.

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