The terrestrial night sky spectrum Is dominated by emission features related to oxygen photochemistry. Photodissociation of molecular oxygen, the second most abundant atmospheric constituent Is the most efficient channel for converting solar electromagnetic radiation into chemical energy. This energy, deposited in the atmosphere during the day is carried by atomic oxygen that eventually initiates a number of chemical reactions leading to the emission of radiation. These processes continue throughout the night and are responsible for the production of the terrestrial nightglow.
A systematic study of the thermospheric oxygen atom distribution and of related optical emission features was conducted with the specific aim of providing the link between the abundance of atomic oxygen and the intensity of nightglow. For this purpose the exact pathways of populating and de-populating the emitting states as well as the excitation and quenching processes have to be known. An attempt to determine these pathways and to understand the basic physics governing the process of the termolecular association of oxygen atoms have been the main objective of the works collected in this thesis.
Within this study a series of rocket experiments, distributed over the years 1975 to 1983, three different geographical sites and varying geophysical conditions have been carried out. These rocket experiments provided an unique set of simultaneous measurements of the oxygen related airglow features and concurrent measurements of atomic oxygen. The first measurement of the 02 Chamberlain system (A'^AU -> a^Ag) altitude profile in the mesopause layer was secured and modelled according to an excitation scheme involving the direct production of the A'^AU (as well as A^SU+) in the termolecular association of oxygen atoms.
Filter photometry alone cannot provide sulficiently detailed spectral information for the unambiguous Interpretation of the rocket-borne airglow measurements. As a continuation and as a necessary complement to the rocket work a ground-based high-resolution spectrometric study of the O2 UV airglow has also been conducted. For the qualitative interpretation of the Oo UV airglow spectra a powerful spectral analysis technique was developed. This method, involving a non-linear least-squares fitting of synthetic spectra to the observations, allows separation of individual bands and the measurement of their column integrated intensity. An exceptional data base of high resolution spectra (0.13 nm|, extending now over half a solar cycle, has been created. From these measurements the vibrational population distribution of the A'JIjj'1' state was obtained and the vibrational population distributions of the two other states (A’^AU and c^£u") were infered. Based on the co-variation studies of the Herzberg I and Herzberg II systems with simultaneously measured green line intensities a set of quenching parameters for 02(c1£u') was obtained. These results Imply that the Herzberg II emission should peak considerably below the Herzberg I and Chamberlain emissions which may explain earlier difficulties in interpreting rocket experiments.