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  • 1.
    Héraly, Frédéric
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Sikdar, Anirban
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Chang, Jian
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Yuan, Jiayin
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Capacitive CO2 sensor made of aminated cellulose nanofibrils: development and optimization2024Ingår i: New Journal of Chemistry, ISSN 1144-0546, E-ISSN 1369-9261, Vol. 48, nr 14, s. 6064-6070Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    CO2 sensors are very important; however, their performance is limited by stability and selectivity. This study unveils a capacitive CO2 sensor with a dielectric layer comprised of amine-functionalized cellulose nanofibril (CNF) foam, significantly enhanced by the addition of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). The core innovation of this research lies in the strategic use of CNF-based foam, which leads to a substantial increase in sensor capacitance, setting a new standard in CO2 monitoring technologies. The sensor showcases exceptional performance under ambient conditions, with marked improvements in sensitivity towards CO2. The advancements are attributed to the chemisorption properties of the aminated CNFs combined with the DBU enhancement, facilitating more effective CO2 capture. By integrating these materials, we present a sensor that opens new avenues for environmental monitoring, healthcare diagnostics, and industrial safety, establishing a new benchmark for capacitive CO2 sensors in efficiency and environmental sustainability.

  • 2.
    Lu, Yahua
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK). Beijing University of Technology, China.
    Zhang, Miao
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Chang, Jian
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Sikdar, Anirban
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Wang, Naixin
    An, Quan-Fu
    Yuan, Jiayin
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Heterostructure membranes of high permeability and stability assembled from MXene and modified layered double hydroxide nanosheets2023Ingår i: Journal of Membrane Science, ISSN 0376-7388, E-ISSN 1873-3123, Vol. 688, artikel-id 122100Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Two-dimensional (2D) MXene-based lamellar membranes play transformative roles in membrane filtration technology. Their practical use in water treatment is however hindered by several hurdles, e.g., unfavorable swelling due to weak interactions between adjacent MXene nanosheets, tortuous diffusion pathways of layered stacking, and the intrinsic aquatic oxidation-prone nature of MXene. Herein, nanoporous 2D/2D heterostructure membranes are elaborately constructed via solution-phase assembly of oppositely charged MXene and modified layered double hydroxide (MLDH) nanosheets. As a multifunctional component, positively charged holey MLDH nanosheets were first tailor-made to serve simultaneously as a binder, spacer and surface-modifier; next they were intercalated into negatively charged MXene lamella to enhance structural stability and mass transfer of membranes. As a result, the as-prepared MLDH@MXene heterostructure membranes successfully break the persistent trade-off between high permeability and selectivity while mitigating the common drawbacks in 2D MXene-based lamellar membranes, e.g., swelling issues, restacking problems, and vulnerable chemical stability. Noticeably, at an operating pressure of 4 bar and a feed solution of 100 ppm of Congo red, the heterostructure membranes enable a threefold jump in permeability (332.7 +/- 20 L m(-2) h(-1 )bar(-1)) when compared to the pristine MXene membrane (119.3 +/- 18 L m(-2 )h(-1) bar(-1)), and better operational stability without compromising the rejection.

  • 3.
    Pang, Kanglei
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Tang, Yaxin
    Qiu, Chunyu
    Zhang, Miao
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Tayal, Akhil
    Feng, Shihui
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Long, Chang
    Wang, Yong-Lei
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Chang, Jian
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Pang, Bo
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Sikdar, Anirban
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Saeedi Garakani, Sadaf
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Zhang, Yu
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Wang, Hong
    Zhang, Weiyi
    Luo, Guangfu
    Wang, Yucheng
    Yuan, Jiayin
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Redirecting configuration of atomically dispersed selenium catalytic sites for efficient hydrazine oxidation2024Ingår i: Matter, ISSN 2590-2393, E-ISSN 2590-2385, Vol. 7, nr 2, s. 655-667Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Understanding the reconstruction of surface sites is crucial for gaining insights into the true active sites and catalytic mechanisms. While extensive research has been conducted on reconstruction behaviors of atomically dispersed metallic catalytic sites, limited attention has been paid to non-metallic ones despite their potential catalytic activity comparable or even superior to their noble-metal counterpart. Herein, we report a carbonaceous, atomically dispersed non-metallic selenium catalyst that displayed exceptional catalytic activity in the hydrazine oxidation reaction (HzOR) in alkaline media, outperforming the noble-metal Pt catalysts. In situ X-ray absorption spectroscopy (XAS) and Fourier transform infrared spectroscopy revealed that the pristine SeC4 site pre-adsorbs an ∗OH ligand, followed by HzOR occurring on the other side of the OH–SeC4. Theoretical calculations proposed that the pre-adsorbed ∗OH group pulls electrons from the Se site, resulting in a more positively charged Se and a higher polarity of Se–C bonds, thereby enhancing surface reactivity toward HzO/R.

  • 4.
    Saeedi Garakani, Sadaf
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Sikdar, Anirban
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Pang, Kanglei
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Yuan, Jiayin
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Poly(ionic liquid)-derived metal-free heteroatom co-doped porous carbons with peroxidase-like activity2024Ingår i: Applied Materials Today, ISSN 2352-9407, Vol. 37, artikel-id 102081Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Development of affordable, efficient and metal-free heterogeneous catalytic systems has been a persistent challenge in academia and industry. Heteroatom-doped metal-free carbon materials are increasingly recognized as valuable heterogeneous catalysts, and if well-designed, can present comparable performance to, or even surpass transition metal-containing catalysts. Their physicochemical properties and structural characteristics are tunable in a wide range, plus being free of leakage problems of transition metal species into the environment. Herein, three types of hierarchically porous N/X co-doped carbon materials (X denotes B, P or S) were synthesized via using poly(ionic liquid)s (PILs) as carbon precursors and source of heteroatom dopants. The incorporation of sacrificial pore-inducing templating agents which created abundant edge defects, in combination with a heteroatom co-doping strategy, enhanced the number of active sites and their peroxidase-like catalytic activities. Comparison with only nitrogen single-doped porous carbons as reference demonstrated that co-doping with nitrogen and another heteroatom exhibits higher peroxidase-like activity and affinity towards substrates. Among the three types of heteroatom co-doped porous carbonaceous artificial enzymes, the N/B co-doped carbonaceous catalyst displayed the highest specific activities and Vmax values. These observations suggest a synergistic effect of the co-dopants, here N and B in the enzyme that holds a promising potential to further enhance peroxidase-like activity.

  • 5.
    Saeedi Garakani, Sadaf
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Zhang, Miao
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Xie, Dongjiu
    Sikdar, Anirban
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Pang, Kanglei
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Yuan, Jiayin
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Facile Fabrication of Wood-Derived Porous Fe3C/Nitrogen-Doped Carbon Membrane for Colorimetric Sensing of Ascorbic Acid2023Ingår i: Nanomaterials, E-ISSN 2079-4991, Vol. 13, nr 20, artikel-id 2786Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    Fe3C nanoparticles hold promise as catalysts and nanozymes, but their low activity and complex preparation have hindered their use. Herein, this study presents a synthetic alternative toward efficient, durable, and recyclable, Fe3C-nanoparticle-encapsulated nitrogen-doped hierarchically porous carbon membranes (Fe3C/N–C). By employing a simple one-step synthetic method, we utilized wood as a renewable and environmentally friendly carbon precursor, coupled with poly(ionic liquids) as a nitrogen and iron source. This innovative strategy offers sustainable, high-performance catalysts with improved stability and reusability. The Fe3C/N–C exhibits an outstanding peroxidase-like catalytic activity toward the oxidation of 3,3′,5,5′-tetramethylbenzidine in the presence of hydrogen peroxide, which stems from well-dispersed, small Fe3C nanoparticles jointly with the structurally unique micro-/macroporous N–C membrane. Owing to the remarkable catalytic activity for mimicking peroxidase, an efficient and sensitive colorimetric method for detecting ascorbic acid over a broad concentration range with a low limit of detection (~2.64 µM), as well as superior selectivity, and anti-interference capability has been developed. This study offers a widely adaptable and sustainable way to synthesize an Fe3C/N–C membrane as an easy-to-handle, convenient, and recoverable biomimetic enzyme with excellent catalytic performance, providing a convenient and sensitive colorimetric technique for potential applications in medicine, biosensing, and environmental fields.

  • 6.
    Sikdar, Anirban
    et al.
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Héraly, Frédéric
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Zhang, Hao
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Hall, Stephen
    Pang, Kanglei
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Zhang, Miao
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Yuan, Jiayin
    Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
    Hierarchically Porous 3D Freestanding Holey-MXene Framework via Mild Oxidation of Self-Assembled MXene Hydrogel for Ultrafast Pseudocapacitive Energy Storage2024Ingår i: ACS Nano, ISSN 1936-0851, E-ISSN 1936-086X, Vol. 18, nr 4, s. 3707-3719Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    The true promise of MXene as a practical supercapacitor electrode hinges on the simultaneous advancement of its three-dimensional (3D) assembly and the engineering of its nanoscopic architecture, two critical factors for facilitating mass transport and enhancing an electrode’s charge-storage performance. Herein, we present a straightforward strategy to engineer robust 3D freestanding MXene (Ti3C2Tx) hydrogels with hierarchically porous structures. The tetraamminezinc(II) complex cation ([Zn(NH3)4]2+) is selected to electrostatically assemble colloidal MXene nanosheets into a 3D interconnected hydrogel framework, followed by a mild oxidative acid-etching process to create nanoholes on the MXene surface. These hierarchically porous, conductive holey-MXene frameworks facilitate 3D transport of both electrons and electrolyte ions to deliver an excellent specific capacitance of 359.2 F g–1 at 10 mV s–1 and superb capacitance retention of 79% at 5000 mV s–1, representing a 42.2% and 15.3% improvement over pristine MXene hydrogel, respectively. Even at a commercial-standard mass loading of 10.1 mg cm–2, it maintains an impressive capacitance retention of 52% at 1000 mV s–1. This rational design of an electrode by engineering nanoholes on MXene nanosheets within a 3D porous framework dictates a significant step forward toward the practical use of MXene and other 2D materials in electrochemical energy storage systems. 

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