Endre søk
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Atomic-Scale Tuning of Tsai-Type Clusters in RE-Au-Si Systems (RE = Gd, Tb, Ho)
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
Vise andre og tillknytning
Rekke forfattare: 82020 (engelsk)Inngår i: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 59, nr 13, s. 9152-9162Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Tsai-type quasicrystals and approximants are distinguished by a cluster unit made up of four concentric polyhedral shells that surround a tetrahedron at the center. Here we show that for Tsai-type 1/1 approximants in the RE-Au-Si systems (RE = Gd, Tb, Ho) the central tetrahedron of the Tsai clusters can be systematically replaced by a single RE atom. The modified cluster is herein termed a pseudo-Tsai cluster and represents, in contrast to the conventional Tsai cluster, a structural motif without internal symmetry breaking. For each system, single-phase samples of both pseudo-Tsai and Tsai-type 1/1 approximants were independently prepared as millimeter-sized, faceted, single crystals using the self-flux synthesis method. The full replacement of tetrahedral moieties by RE atoms in the pseudo-Tsai 1/1 approximants was ascertained by a combination of single-crystal and powder diffraction studies, as well as energy dispersive X-ray spectroscopy (EDX) analyses with a scanning electron microscope (SEM). Differential scanning calorimetry (DSC) studies revealed distinctly higher decomposition temperatures, by 5-35 K, for the pseudo-Tsai phases. Furthermore, the magnetic properties of pseudo-Tsai phases are profoundly and consistently different from the Tsai counterparts. The onset temperatures of magnetic ordering (T-mag) are lowered in the pseudo-Tsai phases by similar to 30% from 24 to 17 K, 11.5 to 8 K, and 5 to 3.5 K in the Gd-Au-Si, Tb-Au-Si, and Ho-Au-Si systems, respectively. In addition, the Tb-Au-Si and Ho-Au-Si systems exhibit some qualitative changes in their magnetic ordering, indicating decisive changes in the magnetic state/structure by a moment-bearing atom at the cluster center.

sted, utgiver, år, opplag, sider
2020. Vol. 59, nr 13, s. 9152-9162
HSV kategori
Identifikatorer
URN: urn:nbn:se:su:diva-184514DOI: 10.1021/acs.inorgchem.0c01023ISI: 000548456300054PubMedID: 32525660OAI: oai:DiVA.org:su-184514DiVA, id: diva2:1466346
Tilgjengelig fra: 2020-09-11 Laget: 2020-09-11 Sist oppdatert: 2022-02-25bibliografisk kontrollert

Open Access i DiVA

Fulltekst mangler i DiVA

Andre lenker

Forlagets fulltekstPubMed

Person

Eklöf, DanielMathieu, RolandHäussermann, Ulrich

Søk i DiVA

Av forfatter/redaktør
Eklöf, DanielMathieu, RolandHäussermann, Ulrich
Av organisasjonen
I samme tidsskrift
Inorganic Chemistry

Søk utenfor DiVA

GoogleGoogle Scholar

doi
pubmed
urn-nbn

Altmetric

doi
pubmed
urn-nbn
Totalt: 87 treff
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf