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Implementation and validation of the relativistic transient absorption theory within the dipole approximation
Stockholms universitet, Naturvetenskapliga fakulteten, Fysikum. Lund University, Sweden.
Stockholms universitet, Naturvetenskapliga fakulteten, Fysikum.ORCID-id: 0000-0003-3444-1317
Rekke forfattare: 42021 (engelsk)Inngår i: Electronic Structure, E-ISSN 2516-1075, Vol. 3, nr 1, artikkel-id 014002Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

A relativistic transient absorption theory is derived, implemented and validated within the dipole approximation based on the time-dependent Dirac equation. In the non-relativistic limit, it is found that the absorption agrees with the well established non-relativistic theory based on the time-dependent Schrodringer equation. Time-dependent simulations have been performed using the Dirac equation and the Schrodinger equation for the hydrogen atom in two different attosecond transient absorption scenarios. These simulations validate the present relativistic theory. The presented work can be seen as a first step in the development of a more general relativistic attosecond transient absorption spectroscopy method for studying heavy atoms, but it also suggests the possibility of studying relativistic effects, such as Zitterbewegung, in the time domain.

sted, utgiver, år, opplag, sider
2021. Vol. 3, nr 1, artikkel-id 014002
Emneord [en]
Attosecond transient absorption, time dependent Dirac equation, relativistic velocity, gauge transformation, Zitterbewegung, power in quantum mechanics
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Identifikatorer
URN: urn:nbn:se:su:diva-194542DOI: 10.1088/2516-1075/abe191ISI: 000645004100003Scopus ID: 2-s2.0-85106955050OAI: oai:DiVA.org:su-194542DiVA, id: diva2:1582678
Merknad

For corrigendum, see: Felipe Zapata et al 2022 Electron. Struct. 4 029501 DOI: 10.1088/2516-1075/ac646f

Tilgjengelig fra: 2021-08-03 Laget: 2021-08-03 Sist oppdatert: 2022-09-30bibliografisk kontrollert

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