Endre søk
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Radiative Stabilization of the Indenyl Cation: Recurrent Fluorescence in a Closed-Shell Polycyclic Aromatic Hydrocarbon
Stockholms universitet, Naturvetenskapliga fakulteten, Fysikum.ORCID-id: 0000-0002-9489-4580
Vise andre og tillknytning
Rekke forfattare: 82025 (engelsk)Inngår i: Physical Review Letters, ISSN 0031-9007, E-ISSN 1079-7114, Vol. 134, nr 22, artikkel-id 228002Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Several small polycyclic aromatic hydrocarbons (PAHs) with closed-shell electronic structure have been identified in the cold, dark environment Taurus Molecular Cloud 1. We measure efficient radiative cooling through the combination of recurrent fluorescence (RF) and IR emission in the closed-shell indenyl cation (C9H7+), finding good agreement with a master equation model including molecular dynamics trajectories to describe internal-energy-dependent properties for RF. We find that C9H7+ formed with up to Ec=5.85 eV vibrational energy, which is ≈2 eV above the dissociation threshold, radiatively cool rather than dissociate. The efficient radiative stabilization dynamics are likely common to other closed-shell PAHs present in space, contributing to their abundance.

sted, utgiver, år, opplag, sider
2025. Vol. 134, nr 22, artikkel-id 228002
HSV kategori
Identifikatorer
URN: urn:nbn:se:su:diva-245946DOI: 10.1103/PhysRevLett.134.228002ISI: 001508634700003PubMedID: 40548801Scopus ID: 2-s2.0-105007831273OAI: oai:DiVA.org:su-245946DiVA, id: diva2:1992803
Tilgjengelig fra: 2025-08-28 Laget: 2025-08-28 Sist oppdatert: 2025-10-06bibliografisk kontrollert

Open Access i DiVA

Fulltekst mangler i DiVA

Andre lenker

Forlagets fulltekstPubMedScopus

Person

Subramani, ArunCederquist, HenrikZettergren, HenningStockett, Mark H.

Søk i DiVA

Av forfatter/redaktør
Subramani, ArunCederquist, HenrikZettergren, HenningStockett, Mark H.
Av organisasjonen
I samme tidsskrift
Physical Review Letters

Søk utenfor DiVA

GoogleGoogle Scholar

doi
pubmed
urn-nbn

Altmetric

doi
pubmed
urn-nbn
Totalt: 15 treff
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf