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Colloidally dispersible activated carbons and yarn-like colloidal assemblies of hydrochar
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).ORCID iD: 0000-0002-8143-8279
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK). Taiyuan University of Technology, China.ORCID iD: 0000-0002-4176-1899
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK). Taiyuan University of Technology, China.ORCID iD: 0000-0002-7284-2974
2023 (English)In: JCIS Open, E-ISSN 2666-934X, Vol. 11, article id 100090Article in journal (Refereed) Published
Abstract [en]

It was hypothesized that activated carbons (ACs) prepared from hydrochar could be dispersed in solvents under certain conditions. The crude hydrochar formed by the hydrothermal carbonization (HTC) of glucose and was purified by dialysis. Dried dispersions of hydrochar were chemically activated with potassium bicarbonate (KHCO3) at temperatures of 750–800 ​°C in N2. The AC prepared from a freeze-dried dispersion of hydrochar could be dispersed in ethanol as 500 nm-sized colloids. It was noted that on regular drying of the hydrochar dispersions, macroscopically large, long, curved, and thin rods of hydrochar formed in the vials. The rods comprised colloidally-packed spherical particles. The rods may have formed from cracked and fractured colloidal coatings and detached from the wall of the vials. This conclusion was supported by analysing the structural features of the rods. The macroscopic shapes were retained on the chemical activation when the hydrochar precursor had been pyrolyzed in N2 before activation. The ACs had specific surface areas of up to 1800 ​m2/g, and CO2 uptake levels of up to 7.1 ​mmol/g at 0 ​°C and 101 ​kPa.

Place, publisher, year, edition, pages
2023. Vol. 11, article id 100090
Keywords [en]
Activated carbon, Dispersions, Assemblies, CO2 adsorption
National Category
Humanities and the Arts
Identifiers
URN: urn:nbn:se:su:diva-233970DOI: 10.1016/j.jciso.2023.100090Scopus ID: 2-s2.0-85165001608OAI: oai:DiVA.org:su-233970DiVA, id: diva2:1902664
Available from: 2024-10-02 Created: 2024-10-02 Last updated: 2024-10-02Bibliographically approved

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Wang, XiaHao, WenmingHedin, Niklas

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