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Resiliency, morphology, and entropic transformations in high-entropy oxide nanoribbons
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).ORCID iD: 0000-0003-4318-8990
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Number of Authors: 212025 (English)In: Science, ISSN 0036-8075, E-ISSN 1095-9203, Vol. 388, no 6750, p. 950-956Article in journal (Refereed) Published
Abstract [en]

We present the successful synthesis and characterization of a one-dimensional high-entropy oxide (1D-HEO) exhibiting nanoribbon morphology. These 1D-HEO nanoribbons exhibit high structural stability at elevated temperatures (to 1000°C), elevated pressures (to 12 gigapascals), and long exposure to harsh acid or base chemical environments. Moreover, they exhibit notable mechanical properties, with an excellent modulus of resilience reaching 40 megajoules per cubic meter. High-pressure experiments reveal an intriguing transformation of the 1D-HEO nanoribbons from orthorhombic to cubic structures at 15 gigapascals followed by the formation of fully amorphous HEOs above 30 gigapascals, which are recoverable to ambient conditions. These transformations introduce additional entropy (structural disorder) besides configurational entropy. This finding offers a way to create low-dimensional, resilient, and high-entropy materials.

Place, publisher, year, edition, pages
2025. Vol. 388, no 6750, p. 950-956
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Nanotechnology for Material Science
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URN: urn:nbn:se:su:diva-244375DOI: 10.1126/science.adr5604ISI: 001500261900022PubMedID: 40440365Scopus ID: 2-s2.0-105007366598OAI: oai:DiVA.org:su-244375DiVA, id: diva2:1971957
Available from: 2025-06-18 Created: 2025-06-18 Last updated: 2025-06-18Bibliographically approved

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Yang, TaiminFeng, ShihuiHuang, Zhehao

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