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Radiative Stabilization of the Indenyl Cation: Recurrent Fluorescence in a Closed-Shell Polycyclic Aromatic Hydrocarbon
Stockholm University, Faculty of Science, Department of Physics.ORCID iD: 0000-0002-9489-4580
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Number of Authors: 82025 (English)In: Physical Review Letters, ISSN 0031-9007, E-ISSN 1079-7114, Vol. 134, no 22, article id 228002Article in journal (Refereed) Published
Abstract [en]

Several small polycyclic aromatic hydrocarbons (PAHs) with closed-shell electronic structure have been identified in the cold, dark environment Taurus Molecular Cloud 1. We measure efficient radiative cooling through the combination of recurrent fluorescence (RF) and IR emission in the closed-shell indenyl cation (C9H7+), finding good agreement with a master equation model including molecular dynamics trajectories to describe internal-energy-dependent properties for RF. We find that C9H7+ formed with up to Ec=5.85 eV vibrational energy, which is ≈2 eV above the dissociation threshold, radiatively cool rather than dissociate. The efficient radiative stabilization dynamics are likely common to other closed-shell PAHs present in space, contributing to their abundance.

Place, publisher, year, edition, pages
2025. Vol. 134, no 22, article id 228002
National Category
Fusion, Plasma and Space Physics
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URN: urn:nbn:se:su:diva-245946DOI: 10.1103/PhysRevLett.134.228002ISI: 001508634700003PubMedID: 40548801Scopus ID: 2-s2.0-105007831273OAI: oai:DiVA.org:su-245946DiVA, id: diva2:1992803
Available from: 2025-08-28 Created: 2025-08-28 Last updated: 2025-10-06Bibliographically approved

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Subramani, ArunCederquist, HenrikZettergren, HenningStockett, Mark H.

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