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Nanocomposite SAC solders: the effect of adding CoPd nanoparticles on the morphology and the shear strength of the Sn–3.0Ag–0.5Cu/Cu solder joints
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
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Number of Authors: 62020 (English)In: Applied Nanoscience, ISSN 2190-5509, E-ISSN 2190-5517, Vol. 10, p. 4603-4607Article in journal (Refereed) Published
Abstract [en]

The effect of bimetallic monodisperse CoPd nanoparticles on the microstructure and the shear strength of the Cu/ SAC305/Cu solder joint was investigated. The nanocomposite Sn–3.0Ag–0.5Cu (SAC305) solders with 0.1, 0.3, 0.5, and 1.0 wt% nanoCoPd were prepared through a paste mixing method. The employed bimetallic nanoparticles were produced via a modified oleylamine method. The microstructural analysis of as-solidified Cu/solder/Cu joints was performed by scanning electron microscopy. The results showed that initial additions of CoPd nanoparticles into the SAC305 solder promoted the growth of the interfacial planar-type Cu3Sn IMC layer; while the average thickness of the interfacial scallop-type Cu6Sn5 IMC layer slightly decreased. Further additions of the nanosized CoPd admixtures to the SAC305 solder paste lead to a significant increase of the average thickness of the Cu6Sn5 intermetallic compound layer up to 40%. The shear strength measurements were performed to investigate a relationship between the microstructure and mechanical properties of the investigated solder joints. The results indicated a decrease in the shear strength of the SAC305 solder joint by addition of 0.1 wt% CoPd NPs, while a difference in absolute values between solder joints with 0.3, 0.5, and 1.0 wt% nanoCoPd was practically insignificant.

Place, publisher, year, edition, pages
2020. Vol. 10, p. 4603-4607
Keywords [en]
Sn–3.0Ag–0.5Cu, CoPd nanoparticles, Microstructure, Shear strength
National Category
Nano Technology
Identifiers
URN: urn:nbn:se:su:diva-185663DOI: 10.1007/s13204-020-01325-xISI: 000564392500001OAI: oai:DiVA.org:su-185663DiVA, id: diva2:1474413
Available from: 2020-10-08 Created: 2020-10-08 Last updated: 2022-02-25Bibliographically approved

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Slabon, Adam

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