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The presence of selected UV filters in a freshwater recreational reservoir and fate in controlled experiments
Stockholm University, Faculty of Science, Department of Environmental Science.
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Number of Authors: 52021 (English)In: Science of the Total Environment, ISSN 0048-9697, E-ISSN 1879-1026, Vol. 754, article id 142373Article in journal (Refereed) Published
Abstract [en]

UV filters present in sunscreen and other cosmetics are directly released into the environment during aquatic recreational activities. The extent to which the wide range of UV filters pose a risk to the environment remains unclear. This study investigated the occurrence and dissipation of selected organic UV filters at a recreational site (Enoggera Reservoir, Queensland, Australia) over 12 h. Furthermore, different possible degradation processes were investigated in a controlled off-site experiment with surface water exposed to natural light. Half-lives were estimated for ten UV filters. In Enoggera Reservoir, seven UV filters were detected, of which the most prevalent were octocrylene, avobenzone (BMDBM) and enzacamene (4-MBC). Summed concentrations of the seven UV filters ranged from 7330 ng L-1 at 13:00 h to 2550 ng L-1 at 21:00 h. In the degradation experiment, four UV filters showed no significant change over time. The fate of these compounds in the environment is likely to be mainly influenced by dispersion. Half-lives of the remaining UV filters were 6.6 h for amiloxate (IMC), 20 h for benzophenone 1, 23 h for octinoxate (EHMC), 30 h for 3-benzylidene camphor, 34 h for 4-MBC and 140 h for dioxybenzone (BP8). The degree of susceptibility to photodegradation and biodegradation was generally consistent within a structural class. The fate and half-lives of UV filters are variable and should be considered on a per site basis when assessing environmental risk.

Place, publisher, year, edition, pages
2021. Vol. 754, article id 142373
Keywords [en]
Sunscreen agents, Personal care products, Degradation, Environmental half-life
National Category
Earth and Related Environmental Sciences
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URN: urn:nbn:se:su:diva-190040DOI: 10.1016/j.scitotenv.2020.142373ISI: 000593907600007PubMedID: 33254898OAI: oai:DiVA.org:su-190040DiVA, id: diva2:1530901
Available from: 2021-02-24 Created: 2021-02-24 Last updated: 2025-02-07Bibliographically approved

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McLachlan, Michael S.O'Brien, Jake W.

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