This introductory chapter addresses the complex interrelations between education policy and education practice developed under new ways of governance. It highlights education nexuses as a concept of its own right and discusses what constitutes the contemporary nexuses in education of today. Based on the cases of education nexuses presented in the volume the chapter summarizes four central characteristics of education nexuses and raise the issue of the need to re-consider how we study education policy and practice in the interface between structure and agency for the future developments in education.